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A GENERAL SYNTHETIC ROUTE TO FULLY N-ALKYLATED AZAMACROCYCLES, AND AN UNCOMMON GEOMETRY FOR A 6-COORDINATE NICKEL(II) COMPLEX OF 1,4,8,11-TETRAPROPYL-1,4,8,11-TETRAAZACYCLOTETRADECANE (L1) - CRYSTAL-STRUCTURE OF TRANS-(R,S,R,S)-[NI(L1)(NCS)2]
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UNSPECIFIED (1991) A GENERAL SYNTHETIC ROUTE TO FULLY N-ALKYLATED AZAMACROCYCLES, AND AN UNCOMMON GEOMETRY FOR A 6-COORDINATE NICKEL(II) COMPLEX OF 1,4,8,11-TETRAPROPYL-1,4,8,11-TETRAAZACYCLOTETRADECANE (L1) - CRYSTAL-STRUCTURE OF TRANS-(R,S,R,S)-[NI(L1)(NCS)2]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS (21). pp. 1573-1575. ISSN 0022-4936
Full text not available from this repository.Abstract
A two-step route to a range of fully N-alkylated azamacrocycles has been developed; the crystal structure of trans-[Ni(L1)(NCS)2] (L1 = 1,4,8,11-tetrapropyl-1,4,8,11-tetraazacyclotetradecane) shows the nickel(II) to be six-coordinate, but with the uncommon (R,S,R,S)-or trans-(l)-set of N-configurations.
| Item Type: | Journal Article |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Journal or Publication Title: | JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS |
| Publisher: | ROYAL SOC CHEMISTRY |
| ISSN: | 0022-4936 |
| Date: | 1 November 1991 |
| Number: | 21 |
| Number of Pages: | 3 |
| Page Range: | pp. 1573-1575 |
| Publication Status: | Published |
| URI: | http://wrap.warwick.ac.uk/id/eprint/22376 |
Data sourced from Thomson Reuters' Web of Knowledge
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