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UNEXPECTED CROWN THIOETHER COMPLEXATION OF VANADIUM(IV) - ISOLATION AND STRUCTURAL CHARACTERIZATION OF [VOCL2([9]ANES3)] ([9]ANES3 = 1,4,7-TRITHIACYCLONONANE)
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UNSPECIFIED (1991) UNEXPECTED CROWN THIOETHER COMPLEXATION OF VANADIUM(IV) - ISOLATION AND STRUCTURAL CHARACTERIZATION OF [VOCL2([9]ANES3)] ([9]ANES3 = 1,4,7-TRITHIACYCLONONANE). JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS (19). pp. 1414-1416. ISSN 0022-4936
Full text not available from this repository.Abstract
Contrary to hard and soft acid-base predictions the 'soft' crown thioether [9]aneS3 forms a stable 1:1 coordination complex with the extremely 'hard' vanadyl ion; [VOCl2([9]aneS3)] has a distorted octahedral structure with facial coordination (endodentate) of the trithiamacrocycle in a [2 + 1] bonding pattern, and provides the first example of a chelated high-valent group V-thioether complex.
| Item Type: | Journal Article |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Journal or Publication Title: | JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS |
| Publisher: | ROYAL SOC CHEMISTRY |
| ISSN: | 0022-4936 |
| Date: | 1 October 1991 |
| Number: | 19 |
| Number of Pages: | 3 |
| Page Range: | pp. 1414-1416 |
| Publication Status: | Published |
| URI: | http://wrap.warwick.ac.uk/id/eprint/22418 |
Data sourced from Thomson Reuters' Web of Knowledge
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