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CONVERSION OF (VINYLKETENE)TRICARBONYLIRON(0) COMPLEXES INTO (VINYLALLENE)TRICARBONYLIRON(0) COMPLEXES
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UNSPECIFIED (1991) CONVERSION OF (VINYLKETENE)TRICARBONYLIRON(0) COMPLEXES INTO (VINYLALLENE)TRICARBONYLIRON(0) COMPLEXES. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS (18). pp. 1290-1292. ISSN 0022-4936.
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Abstract
Addition of phosphonoacetate anions to (vinylketene)tricarbonyliron(0) complexes gave (vinylallene)tricarbonyliron(0) complexes; stereoselectivity as high as 98:2 was observed and the relative stereochemistry of the major stereoisomers was elucidated by X-ray crystal structure analysis of the major isomer of [PhCH = CHC(Me) = C = CHCO2Bu(t)](CO)3Fe0 3d, the product obtained from the reaction between [PhCH = CHC(Me) = C = O](CO)3Fe0 1a and the anion of (EtO)2P(O)CH2CO2Bu(t) 2b.
| Item Type: | Journal Article | ||||
|---|---|---|---|---|---|
| Subjects: | Q Science > QD Chemistry | ||||
| Journal or Publication Title: | JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | ||||
| Publisher: | ROYAL SOC CHEMISTRY | ||||
| ISSN: | 0022-4936 | ||||
| Official Date: | 15 September 1991 | ||||
| Dates: |
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| Number: | 18 | ||||
| Number of Pages: | 3 | ||||
| Page Range: | pp. 1290-1292 | ||||
| Publication Status: | Published |
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