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NMR-STUDIES OF DIFFUSION ANISOTROPY IN METAL HYDRIDE SINGLE-CRYSTALS
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UNSPECIFIED (1991) NMR-STUDIES OF DIFFUSION ANISOTROPY IN METAL HYDRIDE SINGLE-CRYSTALS. JOURNAL OF THE LESS-COMMON METALS, 172 (Part B). pp. 603-610. ISSN 0022-5088.
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Abstract
We report on a theoretical and experimental study of hydrogen diffusion in single crystals of alpha-ScH0.25 and beta-V2H which was concerned with the anisotropy of the NMR relaxation rate R1. In alpha-ScH0.25 we find appreciable anisotropy at low temperature associated with local one-dimensional motion; theory and experiment agree fairly well on both the magnitude and the angular dependence of the anisotropy. In beta-V2H the calculations made use of jump times obtained from neutron scattering. In this case again experiment and theory agree on shape; here experiment gives a larger magnitude.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry T Technology > TN Mining engineering. Metallurgy |
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Journal or Publication Title: | JOURNAL OF THE LESS-COMMON METALS | ||||
Publisher: | ELSEVIER SCIENCE SA LAUSANNE | ||||
ISSN: | 0022-5088 | ||||
Official Date: | 30 August 1991 | ||||
Dates: |
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Volume: | 172 | ||||
Number: | Part B | ||||
Number of Pages: | 8 | ||||
Page Range: | pp. 603-610 | ||||
Publication Status: | Published |
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