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PREPARATION AND CHARACTERIZATION OF NOVEL ORGANOINDIUM DERIVATIVES - X-RAY CRYSTAL-STRUCTURE OF DIMETHYL(SALICYLALDEHYDE)INDIUM
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UNSPECIFIED (1991) PREPARATION AND CHARACTERIZATION OF NOVEL ORGANOINDIUM DERIVATIVES - X-RAY CRYSTAL-STRUCTURE OF DIMETHYL(SALICYLALDEHYDE)INDIUM. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 414 (3). pp. 285-293. ISSN 0022-328X
Full text not available from this repository.Abstract
The reaction of trimethylindium with one equivalent of salicylaldehyde, 2-carboxybenzaldehyde, 2-pyrrolidinone or N,N'-diphenylacetamidine results in the formation of the corresponding dimethylindium derivatives in good yields. The product obtained from the reaction with salicylaldehyde has been shown by a single crystal X-ray diffraction study to consist of centrosymmetric dimers with five-coordinate indium atoms, In-C 2.122(5), In-O(CHO) 2.341(4), In-O(OH) 2.188(3) and 2.383(3) angstrom. The reactions between triethylindium and phenylacetylene and ethanolamine are described.
| Item Type: | Journal Article |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Journal or Publication Title: | JOURNAL OF ORGANOMETALLIC CHEMISTRY |
| Publisher: | ELSEVIER SCIENCE SA LAUSANNE |
| ISSN: | 0022-328X |
| Date: | 27 August 1991 |
| Volume: | 414 |
| Number: | 3 |
| Number of Pages: | 9 |
| Page Range: | pp. 285-293 |
| Publication Status: | Published |
| URI: | http://wrap.warwick.ac.uk/id/eprint/22500 |
Data sourced from Thomson Reuters' Web of Knowledge
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