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MIXED BIDENTATE AND BRIDGING COORDINATION BY FUROIC ACID IN THE X-RAY STRUCTURE OF TRIS(FUROATO)BIS(AQUO)HYDROXODIOXOURANIUM(VI) DIHYDRATE
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UNSPECIFIED (1991) MIXED BIDENTATE AND BRIDGING COORDINATION BY FUROIC ACID IN THE X-RAY STRUCTURE OF TRIS(FUROATO)BIS(AQUO)HYDROXODIOXOURANIUM(VI) DIHYDRATE. Inorganica Chimica Acta, 184 (2). pp. 203-207. ISSN 0020-1693
Full text not available from this repository.Abstract
X-ray diffraction study of the complex [(UO2)2OH(C5H3O3)3(H2O)2].2H2O reveals a unique feature: the uranium(VI) atoms are present as hydroxo-bridged dimers which are linked through carboxylate ligands, to form infinite chains. One UO2 group in the dimer is coordinated by two water molecules, two carboxylate oxygen atoms (bridging it to two adjacent UO2 groups) and the hydroxo O atom. The second UO2 group is coordinated by the hydroxo O atom, two bridging carboxylate oxygen atoms and a chelating bidentate furoate ion.
| Item Type: | Journal Article |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Journal or Publication Title: | Inorganica Chimica Acta |
| Publisher: | ELSEVIER SCIENCE SA LAUSANNE |
| ISSN: | 0020-1693 |
| Date: | 15 June 1991 |
| Volume: | 184 |
| Number: | 2 |
| Number of Pages: | 5 |
| Page Range: | pp. 203-207 |
| Publication Status: | Published |
| URI: | http://wrap.warwick.ac.uk/id/eprint/22567 |
Data sourced from Thomson Reuters' Web of Knowledge
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