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THE MECHANISM OF METHYL RADICAL LOSS FROM CH3CH=CHCH(CH3)OCH3+. AND CH2=C(CH3)CH(CH3)OCH3+. - A NOT-SO-SIMPLE CLEAVAGE
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UNSPECIFIED (1991) THE MECHANISM OF METHYL RADICAL LOSS FROM CH3CH=CHCH(CH3)OCH3+. AND CH2=C(CH3)CH(CH3)OCH3+. - A NOT-SO-SIMPLE CLEAVAGE. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS (15). pp. 1055-1057. ISSN 0022-4936.
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Abstract
Loss of a methyl radical from CH3CH = CHCH(CH3)OCH3+. and CH2 = C(CH3)CH(CH3)OCH3+. is shown by H-2-labelling and collision-induced dissociation experiments to involve elimination of the methyl group originally attached to the double bond, with formation of CH2 = CHC(CH3) = O+CH3 as the fragment ion.
| Item Type: | Journal Article | ||||
|---|---|---|---|---|---|
| Subjects: | Q Science > QD Chemistry | ||||
| Journal or Publication Title: | JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | ||||
| Publisher: | ROYAL SOC CHEMISTRY | ||||
| ISSN: | 0022-4936 | ||||
| Official Date: | 1 August 1991 | ||||
| Dates: |
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| Number: | 15 | ||||
| Number of Pages: | 3 | ||||
| Page Range: | pp. 1055-1057 | ||||
| Publication Status: | Published |
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