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THE MECHANISM OF METHYL RADICAL LOSS FROM CH3CH=CHCH(CH3)OCH3+. AND CH2=C(CH3)CH(CH3)OCH3+. - A NOT-SO-SIMPLE CLEAVAGE

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UNSPECIFIED (1991) THE MECHANISM OF METHYL RADICAL LOSS FROM CH3CH=CHCH(CH3)OCH3+. AND CH2=C(CH3)CH(CH3)OCH3+. - A NOT-SO-SIMPLE CLEAVAGE. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS (15). pp. 1055-1057. ISSN 0022-4936

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Abstract

Loss of a methyl radical from CH3CH = CHCH(CH3)OCH3+. and CH2 = C(CH3)CH(CH3)OCH3+. is shown by H-2-labelling and collision-induced dissociation experiments to involve elimination of the methyl group originally attached to the double bond, with formation of CH2 = CHC(CH3) = O+CH3 as the fragment ion.

Item Type: Journal Article
Subjects: Q Science > QD Chemistry
Journal or Publication Title: JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS
Publisher: ROYAL SOC CHEMISTRY
ISSN: 0022-4936
Date: 1 August 1991
Number: 15
Number of Pages: 3
Page Range: pp. 1055-1057
Publication Status: Published
URI: http://wrap.warwick.ac.uk/id/eprint/22568

Data sourced from Thomson Reuters' Web of Knowledge

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