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REACTIONS OF SB(V) CHLORIDE WITH CROWN ETHERS - FORMATION OF HYDRONIUM ION CROWN-ETHER ANTIMON(V)ATE SALTS
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UNSPECIFIED. (1991) REACTIONS OF SB(V) CHLORIDE WITH CROWN ETHERS - FORMATION OF HYDRONIUM ION CROWN-ETHER ANTIMON(V)ATE SALTS. Inorganica Chimica Acta, 183 (2). pp. 167-171. ISSN 0020-1693
Full text not available from this repository.Abstract
The hydronium ion-crown ether antimon(V)ate salts [(H3O)(18-crown-6)][SbCl6], [(H3O)(12-crown-4)2][SbCl6] and [(H3O)(15-crown-5)][SbCl6] have been isolated from the reactions of SbCl5 and the appropriate crown ether in acetonitrile solution. Identification of these salts follows from microanalytical, IR, Vis-UV, H-1 and Sb-121 NMR data. In one case, viz. SbCl5/15-crown-5/MeCN antimon(V)ate salt formation is accompanied by redox formation ((Sb(V) --> Sb(III)) of the neutral complex SbCl3.15-crown-5. Aspects of the possible routes leading to antimon(v)ate salt and/or redox formation are discussed.
| Item Type: | Journal Article |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Journal or Publication Title: | Inorganica Chimica Acta |
| Publisher: | ELSEVIER SCIENCE SA LAUSANNE |
| ISSN: | 0020-1693 |
| Date: | 15 May 1991 |
| Volume: | 183 |
| Number: | 2 |
| Number of Pages: | 5 |
| Page Range: | pp. 167-171 |
| Publication Status: | Published |
| URI: | http://wrap.warwick.ac.uk/id/eprint/22576 |
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