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REACTIONS OF SB(V) CHLORIDE WITH CROWN ETHERS - FORMATION OF HYDRONIUM ION CROWN-ETHER ANTIMON(V)ATE SALTS

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UNSPECIFIED (1991) REACTIONS OF SB(V) CHLORIDE WITH CROWN ETHERS - FORMATION OF HYDRONIUM ION CROWN-ETHER ANTIMON(V)ATE SALTS. Inorganica Chimica Acta, 183 (2). pp. 167-171.

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Abstract

The hydronium ion-crown ether antimon(V)ate salts [(H3O)(18-crown-6)][SbCl6], [(H3O)(12-crown-4)2][SbCl6] and [(H3O)(15-crown-5)][SbCl6] have been isolated from the reactions of SbCl5 and the appropriate crown ether in acetonitrile solution. Identification of these salts follows from microanalytical, IR, Vis-UV, H-1 and Sb-121 NMR data. In one case, viz. SbCl5/15-crown-5/MeCN antimon(V)ate salt formation is accompanied by redox formation ((Sb(V) --> Sb(III)) of the neutral complex SbCl3.15-crown-5. Aspects of the possible routes leading to antimon(v)ate salt and/or redox formation are discussed.

Item Type: Journal Article
Subjects: Q Science > QD Chemistry
Journal or Publication Title: Inorganica Chimica Acta
Publisher: ELSEVIER SCIENCE SA LAUSANNE
ISSN: 0020-1693
Official Date: 15 May 1991
Dates:
DateEvent
15 May 1991UNSPECIFIED
Volume: 183
Number: 2
Number of Pages: 5
Page Range: pp. 167-171
Publication Status: Published

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