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COLLISION-INDUCED DECOMPOSITION OF PEPTIDES - AN INVESTIGATION INTO THE EFFECT OF COLLISION GAS-PRESSURE ON TRANSLATIONAL ENERGY-LOSSES

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UNSPECIFIED (1991) COLLISION-INDUCED DECOMPOSITION OF PEPTIDES - AN INVESTIGATION INTO THE EFFECT OF COLLISION GAS-PRESSURE ON TRANSLATIONAL ENERGY-LOSSES. ORGANIC MASS SPECTROMETRY, 26 (5). pp. 395-401.

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Abstract

The dependence on the gas pressure of translational energy losses, DELTA-E, suffered by incident ions in collision with helium target gas atoms was investigated for the [M + Na] + ion of valinomycin. DELTA-E was measured from the fragment ion peak positions in the mass-analysed ion kinetic energy (MIKE) spectra. The variation of DELTA-E with target gas pressure was found to be different for different fragment ions. The implications of the results for the number of collisions which may occur under normal collision-induced decomposition conditions (30-40% transmission) are discussed.

Item Type: Journal Article
Subjects: Q Science > QD Chemistry
Q Science > QC Physics
Journal or Publication Title: ORGANIC MASS SPECTROMETRY
Publisher: JOHN WILEY & SONS LTD
ISSN: 0030-493X
Official Date: May 1991
Dates:
DateEvent
May 1991UNSPECIFIED
Volume: 26
Number: 5
Number of Pages: 7
Page Range: pp. 395-401
Publication Status: Published

Data sourced from Thomson Reuters' Web of Knowledge

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