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COLLISION-INDUCED DECOMPOSITION OF PEPTIDES - AN INVESTIGATION INTO THE EFFECT OF COLLISION GAS-PRESSURE ON TRANSLATIONAL ENERGY-LOSSES
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UNSPECIFIED (1991) COLLISION-INDUCED DECOMPOSITION OF PEPTIDES - AN INVESTIGATION INTO THE EFFECT OF COLLISION GAS-PRESSURE ON TRANSLATIONAL ENERGY-LOSSES. ORGANIC MASS SPECTROMETRY, 26 (5). pp. 395-401. ISSN 0030-493X.
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Abstract
The dependence on the gas pressure of translational energy losses, DELTA-E, suffered by incident ions in collision with helium target gas atoms was investigated for the [M + Na] + ion of valinomycin. DELTA-E was measured from the fragment ion peak positions in the mass-analysed ion kinetic energy (MIKE) spectra. The variation of DELTA-E with target gas pressure was found to be different for different fragment ions. The implications of the results for the number of collisions which may occur under normal collision-induced decomposition conditions (30-40% transmission) are discussed.
| Item Type: | Journal Article | ||||
|---|---|---|---|---|---|
| Subjects: | Q Science > QD Chemistry Q Science > QC Physics |
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| Journal or Publication Title: | ORGANIC MASS SPECTROMETRY | ||||
| Publisher: | JOHN WILEY & SONS LTD | ||||
| ISSN: | 0030-493X | ||||
| Official Date: | May 1991 | ||||
| Dates: |
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| Volume: | 26 | ||||
| Number: | 5 | ||||
| Number of Pages: | 7 | ||||
| Page Range: | pp. 395-401 | ||||
| Publication Status: | Published |
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