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STEREOELECTRONIC CONTROL OF THE BASE-CATALYZED REARRANGEMENT OF 2-HYDROXY-3-OXOCARBOXYLATES
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UNSPECIFIED. (1991) STEREOELECTRONIC CONTROL OF THE BASE-CATALYZED REARRANGEMENT OF 2-HYDROXY-3-OXOCARBOXYLATES. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 (3). pp. 381-385. ISSN 0300-9580
Full text not available from this repository.Abstract
The stereochemistry of the alkali-catalysed rearrangement of alpha-acetohydroxybutyrate (2-ethyl-2-hydroxy-3-oxobutanoate) was studied. The rearrangement was found to proceed via a transition state in which a syn arrangement of the C-O bonds is preferred over the anti arrangement by a factor of greater-than-or-equal-to 2:1.
| Item Type: | Journal Article |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Journal or Publication Title: | JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 |
| Publisher: | ROYAL SOC CHEMISTRY |
| ISSN: | 0300-9580 |
| Date: | March 1991 |
| Number: | 3 |
| Number of Pages: | 5 |
| Page Range: | pp. 381-385 |
| Publication Status: | Published |
| URI: | http://wrap.warwick.ac.uk/id/eprint/22806 |
Data sourced from Thomson Reuters' Web of Knowledge
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