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CROWN THIOETHER COMPLEXES OF P-BLOCK ELEMENTS - CRYSTAL AND MOLECULAR-STRUCTURES OF SBCL3.-1,4,7-TRITHIACYCLONONANE AND 2SBCL3.-1,4,7,10,13,16-HEXATHIACYCLOOCTADECANE

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UNSPECIFIED (1991) CROWN THIOETHER COMPLEXES OF P-BLOCK ELEMENTS - CRYSTAL AND MOLECULAR-STRUCTURES OF SBCL3.-1,4,7-TRITHIACYCLONONANE AND 2SBCL3.-1,4,7,10,13,16-HEXATHIACYCLOOCTADECANE. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS (4). pp. 271-272.

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Abstract

The first crown thioether complexes of Sb(III) and Bi(III), as representative p-block elements, have been isolated, viz SbCl3.9S3 1, BiCl3.9S3.0.5 MeCN, SbCl3.15S5, 2SbCl3.18S6 2 and BiCl3.18S6; + X-ray crystal structure determinations of 1 and 2 establish full participation of ligand S-donor sites in metal . . . sulphur bonding in each case.

Item Type: Journal Article
Subjects: Q Science > QD Chemistry
Journal or Publication Title: JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS
Publisher: ROYAL SOC CHEMISTRY
ISSN: 0022-4936
Official Date: 15 February 1991
Dates:
DateEvent
15 February 1991UNSPECIFIED
Number: 4
Number of Pages: 2
Page Range: pp. 271-272
Publication Status: Published

Data sourced from Thomson Reuters' Web of Knowledge

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