UNSPECIFIED. (1991) REACTIONS OF IONIZED NORMAL-PROPAN-1-OL IN THE GAS-PHASE. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 113 (4). pp. 1132-1137. ISSN 0002-7863

Full text not available from this repository.

Abstract

The reactions of metastable ionized n-propan-1-ol have been reinvestigated by means of extensive H-2-labeling experiments. The major fragmentation, by loss of water, proceeds by a specific and unidirectional 1,4-hydrogen migration from the methyl group to the oxygen atom. Collision-induced dissociation of the M.+ and [M-H2O].+ ions is consistent with the involvement of the distonic ion .CH2CH2CH2OH2+ and, probably, the ion-neutral complex CH2CH2CH2.+OH2 in water elimination. A very minor amount of hydrogen atom expulsion also occurs from metastable CH3CH2CH2OH.+ radical cations; this process involves only the alpha-hydrogen atoms. Both water and hydrogen atom losses manifest extremely large deuterium isotope effects.

Item Type:	Journal Article
Subjects:	Q Science > QD Chemistry
Journal or Publication Title:	JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Publisher:	AMER CHEMICAL SOC
ISSN:	0002-7863
Official Date:	13 February 1991
Dates:	Date Event 13 February 1991 UNSPECIFIED
Volume:	113
Number:	4
Number of Pages:	6
Page Range:	pp. 1132-1137
Publication Status:	Published
URI:	http://wrap.warwick.ac.uk/id/eprint/22870

Data sourced from Thomson Reuters' Web of Knowledge

Request changes or add full text files to a record

Actions (login required)

View Item