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REACTIONS OF IONIZED NORMAL-PROPAN-1-OL IN THE GAS-PHASE

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UNSPECIFIED (1991) REACTIONS OF IONIZED NORMAL-PROPAN-1-OL IN THE GAS-PHASE. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 113 (4). pp. 1132-1137.

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Abstract

The reactions of metastable ionized n-propan-1-ol have been reinvestigated by means of extensive H-2-labeling experiments. The major fragmentation, by loss of water, proceeds by a specific and unidirectional 1,4-hydrogen migration from the methyl group to the oxygen atom. Collision-induced dissociation of the M.+ and [M-H2O].+ ions is consistent with the involvement of the distonic ion .CH2CH2CH2OH2+ and, probably, the ion-neutral complex CH2CH2CH2.+OH2 in water elimination. A very minor amount of hydrogen atom expulsion also occurs from metastable CH3CH2CH2OH.+ radical cations; this process involves only the alpha-hydrogen atoms. Both water and hydrogen atom losses manifest extremely large deuterium isotope effects.

Item Type: Journal Article
Subjects: Q Science > QD Chemistry
Journal or Publication Title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Publisher: AMER CHEMICAL SOC
ISSN: 0002-7863
Official Date: 13 February 1991
Dates:
DateEvent
13 February 1991UNSPECIFIED
Volume: 113
Number: 4
Number of Pages: 6
Page Range: pp. 1132-1137
Publication Status: Published

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