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REACTIONS OF ALPHA-PHENYLETHYNYL-TRANS-BETA-STYRYL COMPLEXES WITH ISONITRILES - HEMI-LABILE ALKYNE COORDINATION
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UNSPECIFIED (1991) REACTIONS OF ALPHA-PHENYLETHYNYL-TRANS-BETA-STYRYL COMPLEXES WITH ISONITRILES - HEMI-LABILE ALKYNE COORDINATION. [Journal Item]
Full text not available from this repository.Abstract
Treatment of the complex [Ru{C(C = CPh) = CHPh}Cl(CO)(PPh3)2] (1) with one equivalent of CNR (R = (t)Bu, C6H3Me2-2,6) gives [Ru{C(C = CPh) = CHPh}Cl(CNR)(CO)(PPh3)2]. Addition of a further equivalent of isonitrile and [NH4]PF6 leads to the salts [Ru{C(C = CPh) = CHPh}Cl(CNR)2(CO)(PPh3)2]PF6 and the mixed species [Ru{C(C = CPh) = CHPh}(CO)(CN(t)Bu)(CNC6H3Me2-2,6)(PPh3)2]PF6. The related [Ru{C(C = CPh)=CHPh}(CN(t)Bu)(CO)2(PPh3)2]PF6 is obtained by successive treatment of [Ru(CO)2(PPh3)3] with diphenylbutadiyne, hexafluorophosphoric acid and isonitrile or of 1 with carbon monoxide, AgPF6, and CN(t)Bu.
| Item Type: | Journal Item |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Journal or Publication Title: | JOURNAL OF ORGANOMETALLIC CHEMISTRY |
| Publisher: | ELSEVIER SCIENCE SA LAUSANNE |
| ISSN: | 0022-328X |
| Date: | 22 January 1991 |
| Volume: | 402 |
| Number: | 1 |
| Number of Pages: | 4 |
| Page Range: | C8-C11 |
| Publication Status: | Published |
| URI: | http://wrap.warwick.ac.uk/id/eprint/22872 |
Data sourced from Thomson Reuters' Web of Knowledge
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