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THE COORDINATION CHEMISTRY OF IMINOOXOSULFURANES .10. PSEUDO-OLEFINIC COORDINATION OF OSNC6H4ME-4 TO ZEROVALENT OSMIUM - CRYSTAL-STRUCTURE OF [OSCL(NO)(PPH3)2(OSNC6H4ME-4)]
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UNSPECIFIED (1991) THE COORDINATION CHEMISTRY OF IMINOOXOSULFURANES .10. PSEUDO-OLEFINIC COORDINATION OF OSNC6H4ME-4 TO ZEROVALENT OSMIUM - CRYSTAL-STRUCTURE OF [OSCL(NO)(PPH3)2(OSNC6H4ME-4)]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 401 (3). pp. 357-362. ISSN 0022-328X.
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Abstract
The crystal structure of the complex trans-[OsCl(NO)(PPh3)2(OSNC6H4Me-4)] has been determined and confirms that the sulphur(IV) heterocumulene adopts a pseudo-olefinic mode of coordination (eta-2-NS), with the pyramidal sulphur trans to chloride.
| Item Type: | Journal Article | ||||
|---|---|---|---|---|---|
| Subjects: | Q Science > QD Chemistry | ||||
| Journal or Publication Title: | JOURNAL OF ORGANOMETALLIC CHEMISTRY | ||||
| Publisher: | ELSEVIER SCIENCE SA LAUSANNE | ||||
| ISSN: | 0022-328X | ||||
| Official Date: | 15 January 1991 | ||||
| Dates: |
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| Volume: | 401 | ||||
| Number: | 3 | ||||
| Number of Pages: | 6 | ||||
| Page Range: | pp. 357-362 | ||||
| Publication Status: | Published |
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