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DIASTEREOSELECTIVE FORMATION OF TRICARBONYLIRON(0) COMPLEXES OF 1-AZA-1,3-DIENES BEARING CHIRAL SUBSTITUENTS
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UNSPECIFIED (1991) DIASTEREOSELECTIVE FORMATION OF TRICARBONYLIRON(0) COMPLEXES OF 1-AZA-1,3-DIENES BEARING CHIRAL SUBSTITUENTS. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 (1). pp. 97-101. ISSN 0300-922X.
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Abstract
Syntheses of two series of novel 1-aza-1,3-dienes bearing chiral substituents on nitrogen [PhCH = CHCH = NCH(R)Ph (R = Et, Pr(i) and Bu(t)) and PhCH = CHCH = NCH(R)Me (R = Et, Pr(i) and Bu(t)] are described and the stereochemical outcome of their complexation reactions with Fe2(CO)9 reported. Diastereoisomeric ratios of 93:7 and 94:6 are observed on complexation of PhCH = CHCH = NCH(Bu(t))Ph 10 and PhCH = CHCH = NCH(Bu(t))Me 19 respectively. The structures of the major diastereoisomers of 10 and 19 have been determined by NOE measurements.
| Item Type: | Journal Article | ||||
|---|---|---|---|---|---|
| Subjects: | Q Science > QD Chemistry | ||||
| Journal or Publication Title: | JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | ||||
| Publisher: | ROYAL SOC CHEMISTRY | ||||
| ISSN: | 0300-922X | ||||
| Official Date: | January 1991 | ||||
| Dates: |
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| Number: | 1 | ||||
| Number of Pages: | 5 | ||||
| Page Range: | pp. 97-101 | ||||
| Publication Status: | Published |
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