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DIASTEREOSELECTIVE FORMATION OF TRICARBONYLIRON(0) COMPLEXES OF 1-AZA-1,3-DIENES BEARING CHIRAL SUBSTITUENTS
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UNSPECIFIED (1991) DIASTEREOSELECTIVE FORMATION OF TRICARBONYLIRON(0) COMPLEXES OF 1-AZA-1,3-DIENES BEARING CHIRAL SUBSTITUENTS. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 (1). pp. 97-101. ISSN 0300-922X
Full text not available from this repository.Abstract
Syntheses of two series of novel 1-aza-1,3-dienes bearing chiral substituents on nitrogen [PhCH = CHCH = NCH(R)Ph (R = Et, Pr(i) and Bu(t)) and PhCH = CHCH = NCH(R)Me (R = Et, Pr(i) and Bu(t)] are described and the stereochemical outcome of their complexation reactions with Fe2(CO)9 reported. Diastereoisomeric ratios of 93:7 and 94:6 are observed on complexation of PhCH = CHCH = NCH(Bu(t))Ph 10 and PhCH = CHCH = NCH(Bu(t))Me 19 respectively. The structures of the major diastereoisomers of 10 and 19 have been determined by NOE measurements.
| Item Type: | Journal Article |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Journal or Publication Title: | JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 |
| Publisher: | ROYAL SOC CHEMISTRY |
| ISSN: | 0300-922X |
| Date: | January 1991 |
| Number: | 1 |
| Number of Pages: | 5 |
| Page Range: | pp. 97-101 |
| Publication Status: | Published |
| URI: | http://wrap.warwick.ac.uk/id/eprint/22898 |
Data sourced from Thomson Reuters' Web of Knowledge
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