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The local structure of molecular reaction intermediates at surfaces

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Woodruff, D. P.. (2008) The local structure of molecular reaction intermediates at surfaces. Chemical Society Reviews, Vol.37 (No.10). pp. 2262-2273. ISSN 0306-0012

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Official URL: http://dx.doi.org/10.1039/b719541a

Abstract

A critical review is presented of the results of (experimental) quantitative structural studies of molecular reaction intermediates at surfaces; i.e. molecular species that do not exist naturally in the gas phase and, in most cases, are implicated in surface catalytic processes. A brief review of the main experimental methods that have contributed to this area is followed by a summary of the main results. Investigated species include: carboxylates, RCOO– (particularly formate, but also deprotonated amino acids); methoxy, CH3O–; carbonate, CO3; ethylidyne, CH3C–; NHx and SOx species; cyanide, CN. As far as possible in the limited range of systems studied, a few general trends are identified.

Item Type:	Journal Article
Subjects:	Q Science > QD Chemistry
Divisions:	Faculty of Science > Physics
Library of Congress Subject Headings (LCSH):	Surface chemistry -- Research, Intermediates (Chemistry) -- Research, Organic compounds, Chemistry -- Experiments, Quantitative research
Journal or Publication Title:	Chemical Society Reviews
Publisher:	Royal Society of Chemistry
ISSN:	0306-0012
Date:	2008
Volume:	Vol.37
Number:	No.10
Page Range:	pp. 2262-2273
Identification Number:	10.1039/b719541a
Status:	Peer Reviewed
Access rights to Published version:	Open Access
References:	1 K-M. Schindler, Ph. Hofmann, K-U. Weiss, R. Dippel, V. Fritzsche, A.M. Bradshaw, D.P. Woodruff, M.E. Davila, M.C. Asensio, J.C. Conesa, A.R. Gonzalez-Elipe, J. Electr. Spectros. Rel. Phenom.1 993 64/65, 75 2 P. R. Watson, M. A. Van Hove, K. Hermann. NIST Surface Structure Database Ver. 5.0, NIST Gaithersburg, MD. (2003) 3 J.B. Pendry, Low Energy Electron Diffraction (Academic Press, New York, 1974) 4 M.A. Van Hove, W.H. Weinberg, C.-M. Chan Low-energy electron diffraction: experiment, theory and surface structure. (Springer, Berlin, 1986) 5 K. Heinz, Rep. Prog. Phys. 1995 58, 637 6 D.P. Woodruff, and A.M. Bradshaw Rep. Prog. Phys. 1994 57, 1029 7 D. P. Woodruff, Surf. Sci. Rep. 2007 62, 1. 8 J. Stöhr in X-ray Absorption, Principles, Techniques, Applications of EXAFS, SEXAFS and XANES, ed. R. Prins and D.C. Koeningsberger (Wiley, New York, 1988) 443 9 D.P. Woodruff, Rep. Prog. Phys. 1986 49, 683 10 J. Stöhr, NEXAFS Spectroscopy, Springer-Verlag, Berlin, 1977. 11 J. Stöhr, J.L. Gland, W. Eberhardt, D. Outka, R.J. Madix, F. Sette, R.J. Koestner, U. Doebler, Phys. Rev. Lett. 1983 51, 2414 12 H. Öström, H. Ogasawara, L.Å. Näslund, L.G.M. Pettersson, and A. Nilsson, Phys. Rev. Lett. 2006 96, 146104 13 R. Burch, Phys. Chem. Chem. Phys. 2006 8 5483 14 J. Stöhr, D. Outka, R. J. Madix, and U. Döbler, Phys. Rev. Lett. 1985 54 1256 15 D. Outka, R. J. Madix, and J. Stöhr, Surf. Sci. 1985 164 235 16 A. Puschmann, J. Haase, M. D .Crapper, C. E. Riley, and D. P. Woodruff, Phys. Rev. Lett. 1985 54 2250 17 M. D. Crapper, C. E. Riley, D. P. Woodruff, A. Puschmann, and J. Haase, Surf. Sci. 1986 171, 1 18 D. P. Woodruff, C. F. McConville, A. L. D. Kilcoyne, Th. Lindner, J. Somers, M. Surman, G. Paolucci, and A. M. Bradshaw, Surf. Sci. 1988 201, 228 19 D. B. W. Yawney and R. J. Doedens, Inorg. Chem. 1970 9 1626 20 H. Uekusa, S. Ohba, Y. Saito, M. Kato, T. Tokii, and Y. Muto Acta Cryst. C 1989 45 377 21 M. Yamanaka, H. Uekusa, S. Ohba, Y. Saito, S. Iwata, M. Kato, T. Tokaii, Y. Muto, and O. W. Seward, Acta Cryst. B 1991 47 344 22 F. Sapína, M. Burgos, E. Escrivá, J-V. Folgado, D. Betrán, and P. Gómez-Pomero, Inorganica Chimica Acta 1994 216 185 23 A. Wander, and B. W. Holland, Surf. Sci. 1988 199, L403 24 A. Sotiropoulos, P.K. Milligan, B.C.C. Cowie, and M. Kadodwala Surf. Sci. 2000 444 52 25 Ph. Hofmann, K-M. Schindler, S. Bao, V. Fritzsche, D. E. Ricken, A .M. Bradshaw and D. P. Woodruff, Surf.Sci. 1994 304 74 26 S.M. Johnston, A. Mulligan, V. Dhanak, and M. Kadodwala Surf. Sci. 2003 530 111 27 Th. Lindner, J. Somers, A.M. Bradshaw, A.L.D. Kilcoyne, and D.P. Woodruff Surf. Sci. 1988 203, 333 28 D.A. Outka, R.J. Madix, and J. Stöhr, Surf. Sci. 1985 164 235 29 M. Bader, A. Puschmann and J. Haase, Phys. Rev. B 1986 33 7336 30 E. Holub-Krappe, K.C. Prince, K. Horn and D.P. Woodruff, Surf. Sci. 1986 173 176 31 S.A. Chambers, S. Thevuthasan, Y.J. Kim, G.S. Herman, Z. Wang, E.D. Tober, R.X. Ynzunza, J. Morais, C.H.F. Peden, K. Ferris and C.S. Fadley, Chem. Phys. Lett.1997, 267, 51 32 S. Thevuthasan, G.S. Herman, Y.J. Kim, S.A. Chambers, C.H.F. Peden, Z. Wang, R.X. Ynzunza, E.D. Tober, J. Morais and C.S. Fadley, Surf. Sci. 1998, 401, 261 33 D.I. Sayago, M. Polcik, R. Lindsay, J.T. Hoeft, M. Kittel, R.L.Toomes and D.P.Woodruff, J. Phys. Chem. B 2004 108 14316 34 A. Gutiérrez-Sosa, P. Martínez-Escolano, H. Raza, R. Lindsay, P.L. Wincott and G. Thornton, Surf. Sci. 2001, 471, 163 35 B.E. Hayden, A. King and M.A. Newton, J. Phys. Chem. B 1999, 103, 203 36 P. Käckell and K. Terakura, Surf. Sci. 2000, 461, 191 37 E. A. Kröger, D. I. Sayago, F. Allegretti, M. J. Knight, M. Polcik, W. Unterberger, T. J. Lerotholi, K. A. Hogan, C. L. A. Lamont, M. Cavalleri, K. Hermann, D. P. Woodruff Surf. Sci.2008 602 1267 38 K-U. Weiss, R. Dippel, K-M. Schindler, P. Gardner, V. Fritzsche, A.M. Bradshaw, A.L.D. Kilcoyne and D.P. Woodruff Phys.Rev.Lett. 1992 69 3196 39 S.M. Johnston, G. Rousseau, V. Dhanak, and M. Kadodwala Surf. Sci .2001 477 163 40 M. Pascal, C.L.A. Lamont, M. Kittel, J.T. Hoeft, R. Terborg, M. Polcik, J.H. Kang, R.Toomes and D.P. Woodruff, Surf.Sci.2001 492 285 41 F. Schreiber, Prog. Surf. Sci. 2000 65 151 42 A. Ulman, Chem. Rev. 1996 96 1533 43 D. P. Woodruff, Appl. Surf. Sci. 2007 254 76 44 N.A.Booth, D.P.Woodruff, O.Schaff, T.Gieel, R.Lindsay, P.Baumgartel and A.M.Bradshaw, Surf.Sci. 1998 397 258 45 J.-H. Kang, R. L. Toomes, M. Polcik, M. Kittel, J.-T Hoeft, V. Efstathiou, D. P. Woodruff and A. M. Bradshaw, J.Chem.Phys. 2003 118 6059 46 D.I. Sayago, M. Polcik, G. Nisbet, C.L.A. Lamont and D.P. Woodruff, Surf. Sci. 2005 590 76 47 O.Schaff, G.Hess, V.Fritzsche, V.Fernandez, K.-M.Schindler, A.Theobald, Ph.Hofmann, A.M.Bradshaw, R.Davis and D.P.Woodruff Surf.Sci. 1995 331-333 201 48 M. Kerkar, A.B. Hayden, D.P. Woodruff, M. Kadodwala and R.G. Jones, J. Phys. Condens. Matter 1992 4 5043 49 A.F. Carley, P.R. Davies and G.G. Mariotti, Surf. Sci. 1998 401 400 50 M. Kittel, D.I. Sayago, J.T. Hoeft, M. Polcik, M. Pascal, C.L.A. Lamont, R.L. Toomes, and D.P. Woodruff Surf. Sci 2002 516 237 51 X.-C.Guo and R.J.Madix, Surf.Sci. 2001 489 37 52 X.-C.Guo and R.J.Madix, J.Phys.Chem.B 2001 105 3878 53 J.Robinson and D.P.Woodruff, Surf. Sci. 2004 556 193 54 R.J.Madix, J.L.Solomon and J.Stöhr, Surf.Sci. 1998 197 L253 55 M.Bader, B.Hillert, A.Puschmann, J.Haase and A.M.Bradshaw, Europhys.Lett. 1988 5 443 56 J. E. Demuth , D. E. Eastman, Phys. Rev. Lett. 1974 32 1123 57 S. Lehwald, H. Ibach, Surf. Sci. 1979 89 425 58 S. Bao, Ph. Hofmann, K. -M. Schindler, V. Fritzsche, A. M. Bradshaw, D. P. Woodruff, C. Casado, M. C. Asensio, Surf. Sci. 1994 307-309 722 59 S. Bao, Ph. Hofmann, K. -M. Schindler, V. Fritzsche, A. M. Bradshaw, D. P. Woodruff, C. Casado, M. C .Asensio, Surf. Sci.1995 323 19 60 L.L. Kesmodel, L.H. Dubois and G.A. Somorjai, J. Chem. Phys. 1979 70 2180 61 U. Starke, A. Barbieri, N. Materer, M.A. Van Hove and G.A. Somorjai, Surf. Sci. 1993 286 1 62 R.J. Koestner, M.A. Van Hove and G.A. Somorjai, Surf. Sci. 1982 121 321 63 A. Wander, M.A. Van Hove and G.A. Somorjai, Phys. Rev. Lett. 1991 67 626 64 A. Barbieri, M.A. Van Hove and G.A. Somorjai, in: X.D. Xie, S.Y. Tong, M.A. Van Hove (eds) The Structure of Surfaces IV (World Scientific, Singapore, 1994) 201 65 G.S. Blackman, C.T. Kao, B.E. Bent, C.M. Mate, M.A. Van Hove and G.A. Somorjai, Surf. Sci. 1988 207 66 66 M. J. Knight, F. Allegretti, E. A. Kröger, M. Polcik, C. L. A. Lamont, D. P. Woodruff, to be published 67 R. M. Ormerod, C. J. Baddeley, C. Hardacre, R. M. Lambert, Surf. Sci. 1996 360 1 68 T. E. Caldwell, I. M. Abdelrehim, D. P. Land, J. Am. Chem. Soc. 1996 118 907 69 T. E. Caldwell, D. P. Land, J. Phys. Chem. B 1999 103 7869 70 M. R. Churchill, L. A. Buttrey, J. B. Keister, J. W. Ziller, T. S. Janik, W. S. Striejewske, Organometallics, 1990 9, 766 71 H. Dietrich, K. Jacobi and G. Ertl, J. Chem. Phys. 1997 106 9313 72 B. Afsin, P.R. Davies, A. Pushusky and M.W.Roberts, Surf. Sci. 1991 259 L724 73 B. Afsin, P.R. Davies, A. Pushusky, M.W.Roberts and D. Vincent, Surf. Sci. 1993 284 109 74 C.J.Hirschmugl, K-M.Schindler, O.Schaff, V.Fernandez, A.Theobald, Ph.Hofmann, A.M.Bradshaw, R.Davis, N.A.Booth, D.P.Woodruff and V.Fritzsche Surf.Sci. 1996 352-354 232 75 P.Baumgärtel, R.Lindsay, T.Giessel, O.Schaff A.M.Bradshaw and D.P.Woodruff J.Phys.Chem.B, 2000 104 3044 76 K-M.Schindler, V.Fritzsche, M.C.Asensio, P.Gardner, D.E.Ricken, A.W.Robinson, A.M.Bradshaw, D.P.Woodruff, J.C.Conesa and A.R.Gonzalez-Elipe Phys.Rev.B 1992 46 4836 77 Y. Zheng, E. Moler, E. Hudson, Z. Hussain and D.A. Shirley, Phys. Rev. B 1993 48 4760 78 N.A.Booth, R.Davis, R.Toomes, D.P.Woodruff, C.Hirschmugl, K.-M.Schindler, O.Schaff, V.Fernandez, A.Theobald, Ph.Hofmann, R.Lindsay, T.Gieel, P.Baumgärtel and A.M.Bradshaw, Surf.Sci. 1997 387 152 79 N.Franco, J.Avila, M.E.Davila, M.C.Asensio, D.P.Woodruff, O.Schaff, V.Fernandez, K.-M.Schindler, V.Fritzsche and A.M.Bradshaw Phys.Rev.Lett. 1997 79 673 80 N.Franco, J.Avila, M.E.Davila, M.C.Asensio, D.P.Woodruff, O.Schaff, V.Fernandez, K.-M.Schindler, V.Fritzsche and A.M.Bradshaw J. Phys.: Condens. Matter 1997 9 8419 81 K. Takayanagi, Y. Tanishiro, M. Takahashi, and S. Takahashi, J.Vac.Sci.Technol. A 1985 3 1502 82 M.L. Colaianni, P.J. Chen, and J.T Yates J. Chem. Phys. 1992 96 7826 83 P.J. Chen, M.L. Colaianni, and J.T Yates, Surf. Sci. 1992 274 L605 84 M. Bjrkqvist, M. Gthelid, T. M. Grehk, and U.O. Karlsson, Phys. Rev. B 1998 57 2327 85 S.Bengió, H.Ascolani, N. Franco, J. Avila, M.C. Asensio, A.M. Bradshaw and D.P. Woodruff, Phys.Rev.B 2004 69 125340 86 P. Jakob, Chem. Phys. Lett. 1996 263 607 87 D.R. Mullins, Lj. Kundakovic and S.H. Overbury, J. Catal. 2000 195 169 88 J.H. Miners, A.M. Bradshaw and P. Gardner, Phys. Chem. Chem. Phys. 1999 1 4909 89 F. Huerta, E. Morallón, F. Cases, A. Rodes, J.L. Vázquez and A. Aldaz, J. Electroanal. Chem. 1997 431) 269 90 R.E. Benner, K.U. von Raben, R. Dornhaus, R.K. Chang, B.L. Laube and F.A. Otter, Surf. Sci. 1981 102 7 91 K. Kunimatsu, H. Seki, W.G. Golden, J.G. Gordon II and M.R. Philpott, Surf. Sci. 1985 158 596 92 D.S. Corrigan, P. Gao, L.-W.H. Leung and M.J. Weaver, Langmuir 1986 2 744 93 W. Daum, F. Dederichs and J.E. Müller, Phys. Rev. Lett. 1998 80 766: erratum Phys. Rev. Lett. 2000 85 2655 94 N.A. Booth, R. Davis, D.P. Woodruff, D. Crysostomou, T. McCabe, D.R. Lloyd, O. Schaff, V. Fernandez, S. Bao, K-M. Schindler, R. Lindsay, J.T. Hoeft, R. Terborg, P. Baumgartel and A.M. Bradshaw, Surf. Sci. 1998 416 448 95 D. Brown, D.P. Woodruff, T.C.Q. Noakes and P. Bailey, Surf. Sci 2001 476 L241 96 C. Bittencourt, E.A. Soares and D.P. Woodruff, Surf. Sci. 2003 526 33 97 F. Bondino, A. Baraldi, H. Over, G. Comelli, P. Lacovig, S. Lizzit, G. Paolucci and R. Rosei, Phys. Rev. B 2001 64 085422 98 F. Bondino, E. Vesselli, A. Baraldi, G. Comelli, A. Verdini, A. Cossaro, L. Floreano and A. Morgante, J. Chem. Phys. 2003 118 10735 99 K. Besenthal, G. Chiarello, M.E. Kordesch and H. Conrad, Surf Sci. 1986 178 667 100 M.E. Kordesch, W. Stenzel and H. Conrad, Surf. Sci. 1987 186 601 101 W.H. Wienberg, D.F. Johnson, Y.-Q. Wang, J.E. Parmeter and M.M. Hills, Surf. Sci. 1990 235 L299 102 M.E. Kordesch, W. Feng, W. Stenzel, M. Weaver and H. Conrad, J. Electron Spect. Rel. Phenom. 1987 44 149 103 M.J. Harrison, D.P. Woodruff and J. Robinson, Surf. Sci. 2006 600 340 104 J. Haase, J. Phys.: Condens. Matter 1997 9 3647 105 T. Nakahashi, S. Terada, T. Yokoyama, H. Hamamatsu, Y. Kitajima, M. Sakano, F. Matsui, T. Ohta, Surf. Sci. 373 (1997) 1 106 G .J. Jackson, S. M. Driver, D. P. Woodruff, N. Abrams, R. G .Jones, M. Butterfield, M. D. Crapper, B. C. C. Cowie, V. Formoso, Surf. Sci. 459 (2000) 231 107 G.J. Jackson, D.P. Woodruff, A.S.Y. Chan, R.G. Jones, B.C.C. Cowie, Surf.Sci. 2005 577 31 108 M. J. Harrison, D. P. Woodruff and J. Robinson, Surf. Sci. 2006 600 1827
URI:	http://wrap.warwick.ac.uk/id/eprint/2728