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Isomer separation and gas-phase configurations of organoruthenium anticancer complexes : ion mobility mass spectrometry and modeling
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Williams, Jonathan P., Bugarcic, Tijana, Habtemariam, Abraha, Giles, K. (Kevin), Campuzano, Iain, Rodger, P. Mark and Sadler, P. J.. (2009) Isomer separation and gas-phase configurations of organoruthenium anticancer complexes : ion mobility mass spectrometry and modeling. Journal of The American Society for Mass Spectrometry, Vol.20 (No.6). pp. 1119-1122. ISSN 1044-0305
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Official URL: http://dx.doi.org/10.1016/j.jasms.2009.02.016
Abstract
We have used ion mobility-mass spectrometry combined with molecular modeling for the separation and configurational analysis of three low-molecular-weight isomeric organoruthenium anticancer complexes containing ortho-, meta-, or para-terphenyl arene ligands. The isomers were separated using ion mobility based on traveling-wave technology and the experimentally determined collision cross sections were compared to theoretical calculations. Excellent agreement was observed between the experimentally and theoretically derived measurements. (J Am Soc Mass Spectrom 2009, 20, 1119-1122) (C) 2009 American Society for Mass Spectrometry
| Item Type: | Journal Article | ||||
|---|---|---|---|---|---|
| Subjects: | Q Science > QD Chemistry Q Science > QC Physics |
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| Divisions: | Faculty of Science > Chemistry | ||||
| Library of Congress Subject Headings (LCSH): | Organoruthenium compounds -- Therapeutic use, Organometallic chemistry, Antineoplastic agents, Mass spectrometry, Ion mobility spectroscopy, DNA adducts, Isomers | ||||
| Journal or Publication Title: | Journal of The American Society for Mass Spectrometry | ||||
| Publisher: | Springer New York LLC | ||||
| ISSN: | 1044-0305 | ||||
| Official Date: | June 2009 | ||||
| Dates: |
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| Volume: | Vol.20 | ||||
| Number: | No.6 | ||||
| Number of Pages: | 4 | ||||
| Page Range: | pp. 1119-1122 | ||||
| Identification Number: | 10.1016/j.jasms.2009.02.016 | ||||
| Status: | Peer Reviewed | ||||
| Publication Status: | Published | ||||
| Access rights to Published version: | Restricted or Subscription Access | ||||
| Funder: | Warwick Research Development Fund | ||||
| URI: | http://wrap.warwick.ac.uk/id/eprint/27893 |
Data sourced from Thomson Reuters' Web of Knowledge
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