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Degradation studies of polyurethanes based on vegetable oils. Part 1. Photodegradation
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Mohd Rus, Anika Z., Kemp, T. J. and Clark, Andrew J. (2008) Degradation studies of polyurethanes based on vegetable oils. Part 1. Photodegradation. Progress in Reaction Kinetics and Mechanism, Vol.33 (No.4). pp. 363-391. doi:10.3184/146867808X377140 ISSN 1468-6783.
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Official URL: http://dx.doi.org/10.3184/146867808X377140
Abstract
UV-induced photodegradation has been studied of films of polyurethanes synthesised from (renewable) vegetable materials, namely rapeseed and sunflower oils. The techniques utilised were principally IR and UV-visible spectroscopy. UV(B)-photolysis of the cured films gave rise to IR bands in the carbonyl region at ca 1706 cm(-1) and a UV band at 310 mn attributed to formation of a quinone methide, an assignment supported by the development of new IR bands at 1595, 1650, and 1695 cm(-1) which are typical of this chromophore. In addition, intensification of a band at 1171 cm(-1) is attributed to cross-linking of the soft segments in the polymer.
| Item Type: | Journal Article | ||||
|---|---|---|---|---|---|
| Subjects: | Q Science > QD Chemistry T Technology > TP Chemical technology |
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| Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||
| Library of Congress Subject Headings (LCSH): | Photodegradation, Vegetable oils, Triglycerides, Polymers -- Deterioration | ||||
| Journal or Publication Title: | Progress in Reaction Kinetics and Mechanism | ||||
| Publisher: | Science Reviews 2000 Ltd | ||||
| ISSN: | 1468-6783 | ||||
| Official Date: | 2008 | ||||
| Dates: |
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| Volume: | Vol.33 | ||||
| Number: | No.4 | ||||
| Number of Pages: | 29 | ||||
| Page Range: | pp. 363-391 | ||||
| DOI: | 10.3184/146867808X377140 | ||||
| Status: | Peer Reviewed | ||||
| Publication Status: | Published | ||||
| Access rights to Published version: | Restricted or Subscription Access | ||||
| Funder: | Universiti Tun Hussein Onn Malaysia (UTHM), Malaysian Government | ||||
| Related URLs: |
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