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Enantioselective desymmetrisation of citric acid catalysed by the substrate-tolerant petrobactin biosynthetic enzyme AsbA
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Oves-Costales, Daniel, Song, Lijiang and Challis, Gregory L.. (2009) Enantioselective desymmetrisation of citric acid catalysed by the substrate-tolerant petrobactin biosynthetic enzyme AsbA. Chemical Communications (No.11). pp. 1389-1391. ISSN 1359-7345
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Official URL: http://dx.doi.org/10.1039/b823147h
Abstract
AsbA catalyses the highly enantioselective desymmetrisation of citric acid via ATP-dependent condensation with spermidine, as well as the condensation of citric acid with several spermidine analogues and the condensation of the citric acid analogue tricarballylic acid with spermidine, suggesting that it may be a useful biocatalyst for asymmetric synthesis.
| Item Type: | Journal Article |
|---|---|
| Subjects: | Q Science > QD Chemistry Q Science > QR Microbiology |
| Divisions: | Faculty of Science > Chemistry |
| Library of Congress Subject Headings (LCSH): | Siderophores -- Synthesis, Bacillus anthracis, Spermidine, Condensation, Citric acid, Enantioselective catalysis |
| Journal or Publication Title: | Chemical Communications |
| Publisher: | Royal Society of Chemistry |
| ISSN: | 1359-7345 |
| Date: | 21 March 2009 |
| Number: | No.11 |
| Number of Pages: | 3 |
| Page Range: | pp. 1389-1391 |
| Identification Number: | 10.1039/b823147h |
| Status: | Peer Reviewed |
| Publication Status: | Published |
| Access rights to Published version: | Restricted or Subscription Access |
| Funder: | Biotechnology and Biological Sciences Research Council (Great Britain) (BBSRC) |
| Grant number: | BB/FO13760/1 (BBSRC) |
| URI: | http://wrap.warwick.ac.uk/id/eprint/28392 |
Data sourced from Thomson Reuters' Web of Knowledge
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