Oves-Costales, Daniel, Song, Lijiang and Challis, Gregory L. (2009) Enantioselective desymmetrisation of citric acid catalysed by the substrate-tolerant petrobactin biosynthetic enzyme AsbA. Chemical Communications (No.11). pp. 1389-1391. doi:10.1039/b823147h ISSN 1359-7345.

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Abstract

AsbA catalyses the highly enantioselective desymmetrisation of citric acid via ATP-dependent condensation with spermidine, as well as the condensation of citric acid with several spermidine analogues and the condensation of the citric acid analogue tricarballylic acid with spermidine, suggesting that it may be a useful biocatalyst for asymmetric synthesis.

Item Type:	Journal Article
Subjects:	Q Science > QD Chemistry Q Science > QR Microbiology
Divisions:	Faculty of Science, Engineering and Medicine > Science > Chemistry
Library of Congress Subject Headings (LCSH):	Siderophores -- Synthesis, Bacillus anthracis, Spermidine, Condensation, Citric acid, Enantioselective catalysis
Journal or Publication Title:	Chemical Communications
Publisher:	Royal Society of Chemistry
ISSN:	1359-7345
Official Date:	21 March 2009
Dates:	Date Event 21 March 2009 Published
Number:	No.11
Number of Pages:	3
Page Range:	pp. 1389-1391
DOI:	10.1039/b823147h
Status:	Peer Reviewed
Publication Status:	Published
Access rights to Published version:	Restricted or Subscription Access
Funder:	Biotechnology and Biological Sciences Research Council (Great Britain) (BBSRC)
Grant number:	BB/FO13760/1 (BBSRC)

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