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Two-dimensional Ca-43-H-1 correlation solid-state NMR spectroscopy
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Wong, Alan, Laurencin, Danielle, Dupree, Ray and Smith, Mark E. (2009) Two-dimensional Ca-43-H-1 correlation solid-state NMR spectroscopy. Solid State Nuclear Magnetic Resonance, Vol.35 (No.1). pp. 32-36. doi:10.1016/j.ssnmr.2008.11.002
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Official URL: http://dx.doi.org/10.1016/j.ssnmr.2008.11.002
Abstract
Calcium-43 (nuclear spin, S = 7/2) is an NMR insensitive low-gamma quadrupolar nucleus and up until recently only one-dimensional solid-state Ca-43 NMR spectra have been reported. Through-space correlation experiments are challenging between spin-1/2 and low-gamma quadrupolar nuclei because of the intrinsically weak dipolar interaction and the often-low natural abundance of the quadrupolar nucleus. Rotary-resonance recoupling (R-3) has recently been used to re-introduce hetero-nuclear dipolar interactions for sensitive high-gamma quadrupolar nuclei, but has not yet been applied in the case of low-gamma half-integer quadrupolar nuclei. Here an effective and robust 2D H-1-Ca-43 NMR correlation experiment combining the R-3 dipole-recoupling scheme with 2D HMQC is presented. It is demonstrated that the weak Ca-43-H-1 dipolar coupling in hydroxyapatite and oxy-hydroxyapatite can be readily re-introduced and that this recoupling scheme is more efficient than conventional cross-polarization transfer. Moreover, three Ca-43-H-1 dipolar coupled calcium environments are clearly resolved in the structurally unknown oxy-hydroxyapatite. This local information is not readily available from other techniques such as powder XRD and high resolution electron microscopy. R-3-HMQC is also a desirable experiment because the set-up is simple and it can be applied using conventional multi-resonance probes. (C) 2008 Elsevier Inc. All rights reserved.
| Item Type: | Journal Article | ||||
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| Subjects: | Q Science > QD Chemistry Q Science > QC Physics |
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| Divisions: | Administration > Vice Chancellor's Office Faculty of Science > Physics |
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| Journal or Publication Title: | Solid State Nuclear Magnetic Resonance | ||||
| Publisher: | Academic Press | ||||
| ISSN: | 0926-2040 | ||||
| Official Date: | February 2009 | ||||
| Dates: |
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| Volume: | Vol.35 | ||||
| Number: | No.1 | ||||
| Number of Pages: | 5 | ||||
| Page Range: | pp. 32-36 | ||||
| DOI: | 10.1016/j.ssnmr.2008.11.002 | ||||
| Status: | Peer Reviewed | ||||
| Publication Status: | Published | ||||
| Access rights to Published version: | Restricted or Subscription Access | ||||
| Funder: | Biotechnology and Biological Sciences Research Council (Great Britain) (BBSRC), Engineering and Physical Sciences Research Council (EPSRC), University of Warwick |
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