The Library

An "inside-out" microfluidic approach to monodisperse emulsions stabilized by solid particles

Tools

Nie, Zhihong, Il Park, Jai, Li, Wei, Bon, Stefan Antonius Franciscus and Kumacheva, Eugenia. (2008) An "inside-out" microfluidic approach to monodisperse emulsions stabilized by solid particles. Journal of the American Chemical Society, Vol.130 (No.49). 16508-16509.. ISSN 0002-7863

Full text not available from this repository.

Abstract

We report a versatile "inside-out" microfluidic approach to producing monodisperse particle-stabilized emulsions, as well as supracolloidal polymer microspheres. This approach addresses the challenges faced in conventional strategies for the preparation of Pickering emulsions, that is, an insufficient control of droplet dimensions and an excess of particles in the continuous media. The proposed method minimizes waste of particles, due to their introduction in the droplet phase, rather than in the continuous medium; allows control over the coverage of droplets with particles by manipulating the concentration of particles or the flow rates of the liquids; and provides a route for an easier analysis of the dynamics of formation and buckling of Pickering emulsions.

Item Type: Journal Article
Subjects: Q Science > QD Chemistry
T Technology > TP Chemical technology
Divisions: Faculty of Science > Chemistry
Library of Congress Subject Headings (LCSH): Microfluidics, Stabilizing agents, Emulsions, Liquid-liquid interfaces
Journal or Publication Title: Journal of the American Chemical Society
Publisher: American Chemical Society
ISSN: 0002-7863
Official Date: 10 December 2008
Volume: Vol.130
Number: No.49
Number of Pages: 3
Page Range: 16508-16509.
Identification Number: 10.1021/ja807764m
Status: Peer Reviewed
Publication Status: Published
Access rights to Published version: Restricted or Subscription Access
Funder: Natural Sciences and Engineering Research Council (Canada) (NSERC), Engineering and Physical Sciences Research Council (EPSRC)
References:

(1) Dinsmore, A. D.; F., H. M.; Nikolaides, M. G.; Marquez, M.; Bausch, A. R.;
Weitz, D. A. Science 2002, 298, 1006–1009.
(2) Binks, B. P; Murakami, R. Nat. Mater. 2006, 5, 865–869.
(3) Colver, P. J.; Bon, S. A. F. Chem. Mater. 2007, 19, 1537–1539.
(4) Lin, Y.; Skaff, H.; Boeker, A.; Dinsmore, A. D.; Emrick, T.; Russell, T. P.
J. Am. Chem. Soc. 2003, 125, 12690–12691.
(5) Arumugam, P.; Patra, D.; Samanta, B.; Agasti, S. S.; Subramani, C.; Rotello,
V. M. J. Am. Chem. Soc. 2008, 130, 10046–10047.
(6) Chen, T.; Colver, P. J.; Bon, S. A. F. AdV. Mater. 2007, 19, 2286–2289.
(7) (a) Ramsden, W. Proc. R. Soc. 1903, 72, 156–164. (b) Pickering, S. U.
J. Chem. Soc., Trans. 1907, 91, 2001–2021.
(8) Zeng, C.; Bissig, H.; Dinsmore, D. Solid State Commun. 2006, 139, 547–
556.
(9) Aveyard, R.; Binks, B. P.; Clint, J. H. AdV. Colloid Interface Sci. 2003,
100-102, 503–546.
(10) Studart, A. R.; Gonzenbach, R. T.; Akartuna, I.; Tervoort, E.; Gauckler,
L. J. J. Mater. Chem. 2007, 17, 3283–3289.
(11) Wiley, R. M. J. Colloid Sci. 1954, 9, 427–437.
(12) Thorsen, T.; Roberts, R. W.; Arnold, F. H.; Quake, S. R. Phys. ReV. Lett.
2001, 86, 4163–4166.
(13) Anna, S. L.; Bontoux, N.; Stone, H. A. Appl. Phys. Lett. 2003, 82, 364–
366.
(14) (a) Subramaniam, A. B.; Manouk, A.; Stone, H. A. Nat. Mater. 2005, 4,
553–556. (b) Tice, J. D.; Song, H.; Lyon, A. D.; Ismagilov, R. F. Langmuir
2003, 19, 9127–9133.
(15) Leunissen, M. E.; van Blaaderen, A.; Hollingsworth, A. D.; Sullivan, M. T.;
Chaikin, P. M. Proc. Natl. Acad. Sci. U.S.A. 2007, 104, 2585–2590.
(16) Horozov, T. S.; Aveyard, R.; Binks, B. P.; Clint, J. H. Langmuir 2005, 21,
7405–7412.
URI: http://wrap.warwick.ac.uk/id/eprint/28523

Data sourced from Thomson Reuters' Web of Knowledge

Request changes or add full text files to a record

Actions (login required)

View Item View Item