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Photoactive trans ammine/amine diazido platinum(IV) complexes
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Mackay, Fiona S., Moggach, Stephen A., Collins, Anna, Parsons, S. (Simon) and Sadler, P. J. (2009) Photoactive trans ammine/amine diazido platinum(IV) complexes. Inorganica Chimica Acta, Vol.362 (No.3). pp. 811-819. doi:10.1016/j.ica.2008.02.039 ISSN 0020-1693.
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Official URL: http://dx.doi.org/10.1016/j.ica.2008.02.039
Abstract
The synthesis and characterisation of eight new octahedral Pt-IV complexes of the type trans, trans, trans-[Pt(N-3)(2)(OH)(2)(NH3)(Am)] where Am = methylamine (2), ethylamine (4), thiazole (6), 2-picoline (8), 3-picoline (10), 4-picoline (12), cyclohexylamine (14), and quinoline (16) are reported, including the X-ray crystal structures of complexes 2, 8, and 14 as well as that of two of the precursor Pt-II complexes (trans-[ Pt(N-3)(2)(NH3)(methylamine)] (1) and trans-[Pt(N-3)(2)(NH3)(cyclohexylamine)](13)). Irradiation with UVA light rapidly induces loss in intensity of the azide-to-Pt-IV charge-transfer bands and gives rise to photoreduction of platinum. These complexes have potential for use as photoactivated anticancer agents. (C) 2008 Elsevier B. V. All rights reserved.
| Item Type: | Journal Article | ||||
|---|---|---|---|---|---|
| Subjects: | Q Science > QD Chemistry | ||||
| Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||
| Library of Congress Subject Headings (LCSH): | Photochemistry, Azides, Platinum, X-ray crystallography, Antineoplastic agents | ||||
| Journal or Publication Title: | Inorganica Chimica Acta | ||||
| Publisher: | Elsevier Science SA | ||||
| ISSN: | 0020-1693 | ||||
| Official Date: | 20 February 2009 | ||||
| Dates: |
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| Volume: | Vol.362 | ||||
| Number: | No.3 | ||||
| Number of Pages: | 9 | ||||
| Page Range: | pp. 811-819 | ||||
| DOI: | 10.1016/j.ica.2008.02.039 | ||||
| Status: | Peer Reviewed | ||||
| Publication Status: | Published | ||||
| Access rights to Published version: | Restricted or Subscription Access | ||||
| Funder: | Engineering and Physical Sciences Research Council (EPSRC), Scottish Enterprise, European Cooperation in the Field of Scientific and Technical Research (Organization) |
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