The Library

Synthesis, characterization, and bulk properties of amphiphilic copolymers containing fluorinated methacrylates from sequential copper-mediated radical polymerization

Tools

Hansen, Natanya M. L., Gerstenberg, Michael, Haddleton, David M. and Hvilsted, Soren. (2008) Synthesis, characterization, and bulk properties of amphiphilic copolymers containing fluorinated methacrylates from sequential copper-mediated radical polymerization. Journal of Polymer Science. Part A, Polymer Chemistry, Vol.46 (No.24). pp. 8097-8111. ISSN 0887-624X

Full text not available from this repository.

Abstract

The partly fluorinated monomers, 2,2,2-trifluoroethyl methacrylate (3FM), 2,2,3,3,4,4,5,5-octafluoropentyl methacrylate (8FM), and 1,1,2,2-tetrahydroperfluorodecyl methacrylate (17FM) have been used in the preparation of block copolymers with methyl methacrylate (MMA), 2-methoxyethyl acrylate (MEA), and poly(ethylene glycol) methyl ether methacrylate (PEGMA) by Atom Transfer Radical Polymerization. A kinetic study of the 3FM homopolymerization initiated with ethyl bromoisobutyrate and Cu(I)Br/N-(n-propyl)-2-pyridylmethanimine reveals a living/controlled polymerization in the range 80-110 degrees C, with apparent rate constants of 1.6 . 10(-4) s(-1) to 2.9 . 10(-4) s(-1). Various 3FM containing block copolymers with MMA are prepared by sequential monomer addition or from a PMMA macroinitiator in all cases with controlled characteristics. Block copolymers of 3FM and PEGMA resulted in block copolymers with PDI < 1.22, whereas block copolymers from 3FM and MEA have less controlled characteristics. The block copolymers based on MMA with 8FM and 17 FM have PDI's < 1.30. The glass transition temperatures of the block copolymers are dominated by the majority monomer, as the sequential monomer addition results in too short pure blocks to induce observable microphase separation. The thermal stability of the fluorinated poly((meth)acrylate)s in inert atmosphere is less than that of corresponding nonfluorinated poly((meth)acrylate)s. The presence of fluorinated blocks significantly increases the advancing water contact angle of thin films compared to films of the nonfluorinated poly((meth)acrylate)s. (C) 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 8097-8111, 2008

Item Type: Journal Article
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science > Chemistry
Library of Congress Subject Headings (LCSH): Amphiphiles, Polymerization, Block copolymers, Fluoropolymers, Monomers
Journal or Publication Title: Journal of Polymer Science. Part A, Polymer Chemistry
Publisher: John Wiley & Sons, Inc.
ISSN: 0887-624X
Official Date: 15 December 2008
Volume: Vol.46
Number: No.24
Number of Pages: 15
Page Range: pp. 8097-8111
Identification Number: 10.1002/pola.23107
Status: Peer Reviewed
Publication Status: Published
Access rights to Published version: Restricted or Subscription Access
Funder: Novo Nordisk
References:

1. Hansen, N. M. L; Jankova, K.; Hvilsted, S. Eur
Polym J 2007, 43, 255–293.
2. Roche, V.; Vacandio, F.; Bertin, D.; Massiani, Y. J
Electroceram 2006, 16, 41–47.
3. Jankova, K.; Jannasch, P.; Hvilsted, S. J Mater
Chem 2004, 14, 2902–2908.
4. Fu, G. D.; Kang, E. T.; Neoh, K. G.; Lin, C. C.;
Liaw, D. J. Macromolecules 2005, 38, 7593–7600.
5. Eberhardt, M.; Theato, P. Macromol Rapid Commun
2005, 26, 1488–1493.
6. Inoue, Y.; Watanabe, J.; Takai, M.; Yusa, S.; Ishihara,
K. J Polym Sci Part A: Polym Chem 2005,
43, 6073–6083.
7. (a) Kato, M.; Kamigaito, M.; Sawamoto, M.; Higashimura,
T. Macromolecules 1995, 28, 1721–1723;
(b) Wang, J. S.; Matyjaszewski, K. J Am Chem
Soc 1995, 117, 5614–5615.
8. Betts, D.; Johnson, T.; LeRoux, D.; DeSimone, J.
M. In New Materials by Controlled Radical Polymerization,
ACS Symposion Series 1998; Chapter
25, pp 418–432.
9. Li, K.; Wu, P. P.; Han, Z. W. Polymer 2002, 43,
4079–4086.
10. Perrier, S.; Jackson, S. G.; Haddleton, D. M.;
Ameduri, B.; Boutevin, B. Macromolecules 2003,
36, 9042–9049.
11. Zhang, Z. B.; Ying, S. K.; Hu, Q. H.; Xu, X. D. J
Appl Polym Sci 2002, 83, 2625–2633.
12. Xia, J. H.; Johnson, T.; Gaynor, S. G.; Matyjaszewski,
K.; DeSimone, J. Macromolecules 1999,
32, 4802–4805.
13. Li, H.; Zhang, Z. B.; Hu, C. P.; Ying, S. K.; Wu, S.
S.; Xu, X. D. React Funct Polym 2003, 56, 189–
197.
14. Shemper, B. S.; Mathias, L. J. Eur Polym J 2004,
40, 651–665.
15. Lim, K. T.; Lee, M. Y.; Moon, M. J.; Lee, G. D.;
Hong, S. S.; Dickson, J. L.; Johnston, K. P. Polymer
2002, 43, 7043–7049.
16. Hussain, H.; Budde, H.; Horing, S.; Kressler, J.
Macromol Chem Phys 2002, 203, 2103–2112.
17. Luo, Z. H.; He, T. Y. React Funct Polym 2008, 68,
931–942.
18. Shunmugam, R.; Smith, C. E.; Tew, G. N. J Polym
Sci Part A: Polym Chem 2007, 45, 2601–2608.
19. Villarroya, S.; Zhou, J. X.; Duxbury, C. J.; Heise, A.;
Howdle, S. M.Macromolecules 2006, 39, 633–640.
20. Granville, A. M.; Brittain, W. J. Macromol Rapid
Commun 2004, 25, 1298–1302.
21. Chen, R. X.; Feng, C.; Zhu, S. P.; Botton, G.; Ong,
B.; Wu, Y. L. J Polym Sci Part A: Polym Chem
2006, 44, 1252–1262.
22. Tanaka, M. Bio Med Mater Eng 2004, 14, 427–
438.
23. Tanaka, M.; Mochizuki, A. J Biomed Mater Res
Part A 2004, 68A, 684–695.
24. Li, G. F.; Shen, Y.; Morita, S.; Nishida, T.; Osawa,
M. J Am Chem Soc 2004, 126, 12198–12199.
25. Bednarek, M.; Jankova, K.; Hvilsted, S. J Polym
Sci Part A: Polym Chem 2007, 45, 333–340.
26. Hansen, N. M. L.; Haddleton, D. M.; Hvilsted, S.
J Polym Sci Part A: Polym Chem 2007, 45, 5770–
5780.
27. Keller, R. N.; Wycoff, H. D. Inorg Synth 1946, 2,
1–4.
28. Haddleton, D. M.; Crossman, M. C.; Dana, B. H.;
Duncalf, D. J.; Heming, A. M.; Kukulj, D.; Shooter,
A. J. Macromolecules 1999, 32, 2110–2119.
29. Qiu, J.; Matyjaszewski, K. Macromolecules 1997,
30, 5643–5648.
30. Jankova, K.; Hvilsted, S. Macromolecules 2003,
36, 1753–1758.
31. Hvilsted, S.; Borkar, S.; Siesler, H. W.; Jankova,
K. In Advances in Controlled/Living Radical Polymerization;
Matyjaszewski, K., Ed.; ACS Symposion
Series Vol 854; American Chemical Society:
Washington, DC, 2003; Chapter 17, pp 236–249.
32. Haddleton, D. M.; Kukulj, D.; Duncalf, D. J.;
Heming, A. M.; Shooter, A. J. Macromolecules
1998, 31, 5201–5205.
33. Perrier, S.; Haddleton, D. M. Eur Polym J 2004,
40, 2277–2286.
34. Lecolley, F. Ph.D. Thesis, New Polymers from Living
Radical Polymerisation for Biological Applications,
University of Warwick, UK, 2004, Chapter
3, Synthesis and Characterization of N-succinimidyl
ester functionalized Poly(mPEGMA).
35. Ali, M. M.; Sto¨ver, H. D. H. Macromolecules 2003,
36, 1793–1801.
36. Ydens, I.; Dege´e, P.; Haddleton, D. M.; Dubois, P.
Eur Polym J 2005, 41, 2255–2263.
37. Zuev, V. V.; Bertini, F.; Audisio, G. Polym Degrad
Stab 2006, 91, 512–516.
38. Borkar, S.; Jankova, K.; Siesler, H. W.; Hvilsted,
S. Macromolecules 2004, 37, 788–794.
39. Wang, J. G.; Ober, C. K. Macromolecules 1997,
30, 7560–7567.
URI: http://wrap.warwick.ac.uk/id/eprint/28827

Data sourced from Thomson Reuters' Web of Knowledge

Request changes or add full text files to a record

Actions (login required)

View Item View Item