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Control of polymorphism in NaNbO3 by hydrothermal synthesis
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Modeshia, Deena R., Darton, Richard J., Ashbrook, Sharon E. and Walton, Richard I.. (2009) Control of polymorphism in NaNbO3 by hydrothermal synthesis. Chemical Communications, Vol.45 (No.1). pp. 68-70. ISSN 1359-7345
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Official URL: http://dx.doi.org/10.1039/b814601b
Abstract
The metastable ilmenite polymorph of NaNbO3, instead of the expected perovskite polymorph, may be prepared directly in one step under mild hydrothermal conditions by lowering pH and using close to stoichiometric amounts of metal precursors; in situ energy-dispersive X-ray diffraction shows that crystallisation occurs rapidly via a sequence of intermediate crystalline phases.
| Item Type: | Journal Article |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Divisions: | Faculty of Science > Chemistry |
| Library of Congress Subject Headings (LCSH): | Polymorphism (Crystallography), Thermochemistry, Biosynthesis, Nuclear magnetic resonance, Crystallization, Oxides, Lead zirconate titanate, Sodium compounds |
| Journal or Publication Title: | Chemical Communications |
| Publisher: | Royal Society of Chemistry |
| ISSN: | 1359-7345 |
| Date: | 2009 |
| Volume: | Vol.45 |
| Number: | No.1 |
| Number of Pages: | 3 |
| Page Range: | pp. 68-70 |
| Identification Number: | 10.1039/b814601b |
| Status: | Peer Reviewed |
| Publication Status: | Published |
| Access rights to Published version: | Restricted or Subscription Access |
| Funder: | Engineering and Physical Sciences Research Council (EPSRC) |
| Grant number: | EP/F012721/1 (EPSRC) |
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| URI: | http://wrap.warwick.ac.uk/id/eprint/28936 |
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