The Library
Platinum(IV) complexes : C-H activation at low temperatures
Tools
Tools
Tools
Mamtora, Jemini, Crosby, Sarah H., Newman, Christopher P., Clarkson, Guy J. and Rourke, Jonathan (2008) Platinum(IV) complexes : C-H activation at low temperatures. Organometallics, Vol.27 (No.21). pp. 5559-5565. doi:10.1021/om800583c ISSN 0276-7333.
Research output not available from this repository.
Request-a-Copy directly from author or use local Library Get it For Me service.
Official URL: http://dx.doi.org/10.1021/om800583c
Abstract
The oxidation of square-planar cyclometalated Pt(II) phenylpyridine species using the electrophilic chlorine based oxidant PhICl2 has been studied. Rapid oxidations are observed in chloroform solvent at -40 degrees C leading to single products. In acetone solvent isomeric forms of the product are formed, and these are observed to isomerize at around -10 degrees C. The oxidation of a complex with an uncyclometalated pendant arm resulted in the very rapid cyclometalation of that arm by the resulting electrophilic Pt(IV) species.
| Item Type: | Journal Article | ||||
|---|---|---|---|---|---|
| Subjects: | Q Science > QD Chemistry | ||||
| Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||
| Library of Congress Subject Headings (LCSH): | Platinum group, Complex compounds, Oxidation, Chloroform | ||||
| Journal or Publication Title: | Organometallics | ||||
| Publisher: | American Chemical Society | ||||
| ISSN: | 0276-7333 | ||||
| Official Date: | 10 November 2008 | ||||
| Dates: |
|
||||
| Volume: | Vol.27 | ||||
| Number: | No.21 | ||||
| Number of Pages: | 7 | ||||
| Page Range: | pp. 5559-5565 | ||||
| DOI: | 10.1021/om800583c | ||||
| Status: | Peer Reviewed | ||||
| Publication Status: | Published |
Data sourced from Thomson Reuters' Web of Knowledge
Request changes or add full text files to a record
Repository staff actions (login required)
 |
View Item |
