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Concise synthesis of key 3-polyenoyl-5-methylenefuran-2,4-dione putative intermediates in quartromicin biosynthesis

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Montgomery, Laura J. and Challis, Gregory L. (2008) Concise synthesis of key 3-polyenoyl-5-methylenefuran-2,4-dione putative intermediates in quartromicin biosynthesis. Synlett (No.14). pp. 2164-2168. doi:10.1055/s-2008-1078247 ISSN 0936-5214.

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Official URL: http://dx.doi.org/10.1055/s-2008-1078247

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Abstract

Concise syntheses of two 3-polyenoyl-5-methylenefuran-2,4-diones, which are proposed to be key intermediates in the biosynthesis of the unusual 32-membered carbocycle-containing quartromicin antibiotics, are reported involving acylation of 3-lithio-4-methoxy-5-methylene-5H-furan-2-one as a key step.

Item Type: Journal Article
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science, Engineering and Medicine > Science > Chemistry
Library of Congress Subject Headings (LCSH): Antibiotics -- Synthesis
Journal or Publication Title: Synlett
Publisher: Georg Thieme Verlag
ISSN: 0936-5214
Official Date: 22 August 2008
Dates:
DateEvent
22 August 2008Published
Number: No.14
Number of Pages: 5
Page Range: pp. 2164-2168
DOI: 10.1055/s-2008-1078247
Status: Peer Reviewed
Publication Status: Published
Access rights to Published version: Restricted or Subscription Access
Funder: Engineering and Physical Sciences Research Council (EPSRC)

Data sourced from Thomson Reuters' Web of Knowledge

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