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Concise synthesis of key 3-polyenoyl-5-methylenefuran-2,4-dione putative intermediates in quartromicin biosynthesis
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Montgomery, Laura J. and Challis, Gregory L. (2008) Concise synthesis of key 3-polyenoyl-5-methylenefuran-2,4-dione putative intermediates in quartromicin biosynthesis. Synlett (No.14). pp. 2164-2168. doi:10.1055/s-2008-1078247 ISSN 0936-5214.
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Official URL: http://dx.doi.org/10.1055/s-2008-1078247
Abstract
Concise syntheses of two 3-polyenoyl-5-methylenefuran-2,4-diones, which are proposed to be key intermediates in the biosynthesis of the unusual 32-membered carbocycle-containing quartromicin antibiotics, are reported involving acylation of 3-lithio-4-methoxy-5-methylene-5H-furan-2-one as a key step.
| Item Type: | Journal Article | ||||
|---|---|---|---|---|---|
| Subjects: | Q Science > QD Chemistry | ||||
| Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||
| Library of Congress Subject Headings (LCSH): | Antibiotics -- Synthesis | ||||
| Journal or Publication Title: | Synlett | ||||
| Publisher: | Georg Thieme Verlag | ||||
| ISSN: | 0936-5214 | ||||
| Official Date: | 22 August 2008 | ||||
| Dates: |
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| Number: | No.14 | ||||
| Number of Pages: | 5 | ||||
| Page Range: | pp. 2164-2168 | ||||
| DOI: | 10.1055/s-2008-1078247 | ||||
| Status: | Peer Reviewed | ||||
| Publication Status: | Published | ||||
| Access rights to Published version: | Restricted or Subscription Access | ||||
| Funder: | Engineering and Physical Sciences Research Council (EPSRC) |
Data sourced from Thomson Reuters' Web of Knowledge
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