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Effect of the nature of the metal on the breathing steps in MOFs with dynamic frameworks

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Millange, Franck, Guillou, Nathalie, Walton, Richard I., Greneche, Jean-Marc, Margiolaki, Irene and Fereya, Gerard (2008) Effect of the nature of the metal on the breathing steps in MOFs with dynamic frameworks. Chemical Communications (No.39). pp. 4732-4734. doi:10.1039/b809419e

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Official URL: http://dx.doi.org/10.1039/b809419e

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Abstract

The thermal behaviour of the nanoporous iron(III) terephthalate MIL-53 is in stark contrast to its chromium and aluminium analogues which show an expansion of the cell during dehydration; with iron, reversible dehydration occurs via evolution of the structure through a highly distorted metastable anhydrous phase to a more regular phase above 423 K in which pore volume remains approximately constant.

Item Type: Journal Article
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science > Chemistry
Library of Congress Subject Headings (LCSH): Porous materials, Crystallography, Iron, Thermochemistry
Journal or Publication Title: Chemical Communications
Publisher: Royal Society of Chemistry
ISSN: 1359-7345
Official Date: 2008
Dates:
DateEvent
2008Published
Number: No.39
Number of Pages: 3
Page Range: pp. 4732-4734
DOI: 10.1039/b809419e
Status: Peer Reviewed
Publication Status: Published
Funder: Centre national de la recherche scientifique (France) (CNRS), France. Agence nationale de la recherche (ANR), European Union (EU)

Data sourced from Thomson Reuters' Web of Knowledge

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