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Effect of the nature of the metal on the breathing steps in MOFs with dynamic frameworks
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Millange, Franck, Guillou, Nathalie, Walton, Richard I., Greneche, Jean-Marc, Margiolaki, Irene and Fereya, Gerard (2008) Effect of the nature of the metal on the breathing steps in MOFs with dynamic frameworks. Chemical Communications (No.39). pp. 4732-4734. doi:10.1039/b809419e
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Official URL: http://dx.doi.org/10.1039/b809419e
Abstract
The thermal behaviour of the nanoporous iron(III) terephthalate MIL-53 is in stark contrast to its chromium and aluminium analogues which show an expansion of the cell during dehydration; with iron, reversible dehydration occurs via evolution of the structure through a highly distorted metastable anhydrous phase to a more regular phase above 423 K in which pore volume remains approximately constant.
| Item Type: | Journal Article | ||||
|---|---|---|---|---|---|
| Subjects: | Q Science > QD Chemistry | ||||
| Divisions: | Faculty of Science > Chemistry | ||||
| Library of Congress Subject Headings (LCSH): | Porous materials, Crystallography, Iron, Thermochemistry | ||||
| Journal or Publication Title: | Chemical Communications | ||||
| Publisher: | Royal Society of Chemistry | ||||
| ISSN: | 1359-7345 | ||||
| Official Date: | 2008 | ||||
| Dates: |
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| Number: | No.39 | ||||
| Number of Pages: | 3 | ||||
| Page Range: | pp. 4732-4734 | ||||
| DOI: | 10.1039/b809419e | ||||
| Status: | Peer Reviewed | ||||
| Publication Status: | Published | ||||
| Funder: | Centre national de la recherche scientifique (France) (CNRS), France. Agence nationale de la recherche (ANR), European Union (EU) |
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