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Effect of the nature of the metal on the breathing steps in MOFs with dynamic frameworks
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Millange, Franck, Guillou, Nathalie, Walton, Richard I., Greneche, Jean-Marc, Margiolaki, Irene and Fereya, Gerard (2008) Effect of the nature of the metal on the breathing steps in MOFs with dynamic frameworks. Chemical Communications (No.39). pp. 4732-4734. doi:10.1039/b809419e ISSN 1359-7345.
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Official URL: http://dx.doi.org/10.1039/b809419e
Abstract
The thermal behaviour of the nanoporous iron(III) terephthalate MIL-53 is in stark contrast to its chromium and aluminium analogues which show an expansion of the cell during dehydration; with iron, reversible dehydration occurs via evolution of the structure through a highly distorted metastable anhydrous phase to a more regular phase above 423 K in which pore volume remains approximately constant.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||
Library of Congress Subject Headings (LCSH): | Porous materials, Crystallography, Iron, Thermochemistry | ||||
Journal or Publication Title: | Chemical Communications | ||||
Publisher: | Royal Society of Chemistry | ||||
ISSN: | 1359-7345 | ||||
Official Date: | 2008 | ||||
Dates: |
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Number: | No.39 | ||||
Number of Pages: | 3 | ||||
Page Range: | pp. 4732-4734 | ||||
DOI: | 10.1039/b809419e | ||||
Status: | Peer Reviewed | ||||
Publication Status: | Published | ||||
Funder: | Centre national de la recherche scientifique (France) (CNRS), France. Agence nationale de la recherche (ANR), European Union (EU) |
Data sourced from Thomson Reuters' Web of Knowledge
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