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Novel purely organic conductor with an aminoxyl radical, alpha-(BEDT-TTF)(2)(PO-CONHCH2SO3)-2H(2)O (PO=2,2,5,5-tetramethyl-3-pyrrolin-1-oxyl free radical)
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Akutsu, Hiroki, Yamashita, S. (Shinji), Yamada, Jun-ichi, Nakatsuji, Shin'ichi and Turner, S. S. (Scott S.) (2008) Novel purely organic conductor with an aminoxyl radical, alpha-(BEDT-TTF)(2)(PO-CONHCH2SO3)-2H(2)O (PO=2,2,5,5-tetramethyl-3-pyrrolin-1-oxyl free radical). Chemistry Letters, Vol.37 (No.8). pp. 882-883. doi:10.1246/cl.2008.882
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Official URL: http://dx.doi.org/10.1246/cl.2008.882
Abstract
A novel bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF)-based salt with an aminoxyl radical 2,2,5,5-tetramethyl-3-pyrrolin-l-oxyl (PO) has been prepared. The salt has alpha-type 2-D conducting sheets and is a semiconductor with rho(RT) = 26 Omega center dot cm and E-a = 0.31 eV. The temperature dependence of the magnetic susceptibility suggests that both the aminoxyl radical and the BEDT-TTF layer have local spin moments at room temperature.
| Item Type: | Journal Article | ||||
|---|---|---|---|---|---|
| Subjects: | Q Science > QD Chemistry | ||||
| Divisions: | Faculty of Science > Chemistry | ||||
| Library of Congress Subject Headings (LCSH): | Organic conductors, Radicals (Chemistry) | ||||
| Journal or Publication Title: | Chemistry Letters | ||||
| Publisher: | Chemical Society of Japan | ||||
| ISSN: | 0366-7022 | ||||
| Official Date: | 5 August 2008 | ||||
| Dates: |
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| Volume: | Vol.37 | ||||
| Number: | No.8 | ||||
| Number of Pages: | 2 | ||||
| Page Range: | pp. 882-883 | ||||
| DOI: | 10.1246/cl.2008.882 | ||||
| Status: | Peer Reviewed | ||||
| Publication Status: | Published | ||||
| Access rights to Published version: | Restricted or Subscription Access |
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