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Novel purely organic conductor with an aminoxyl radical, alpha-(BEDT-TTF)(2)(PO-CONHCH2SO3)-2H(2)O (PO=2,2,5,5-tetramethyl-3-pyrrolin-1-oxyl free radical)

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Akutsu, Hiroki, Yamashita, S. (Shinji), Yamada, Jun-ichi, Nakatsuji, Shin'ichi and Turner, S. S. (Scott S.) (2008) Novel purely organic conductor with an aminoxyl radical, alpha-(BEDT-TTF)(2)(PO-CONHCH2SO3)-2H(2)O (PO=2,2,5,5-tetramethyl-3-pyrrolin-1-oxyl free radical). Chemistry Letters, Vol.37 (No.8). pp. 882-883. doi:10.1246/cl.2008.882

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Official URL: http://dx.doi.org/10.1246/cl.2008.882

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Abstract

A novel bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF)-based salt with an aminoxyl radical 2,2,5,5-tetramethyl-3-pyrrolin-l-oxyl (PO) has been prepared. The salt has alpha-type 2-D conducting sheets and is a semiconductor with rho(RT) = 26 Omega center dot cm and E-a = 0.31 eV. The temperature dependence of the magnetic susceptibility suggests that both the aminoxyl radical and the BEDT-TTF layer have local spin moments at room temperature.

Item Type: Journal Article
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science > Chemistry
Library of Congress Subject Headings (LCSH): Organic conductors, Radicals (Chemistry)
Journal or Publication Title: Chemistry Letters
Publisher: Chemical Society of Japan
ISSN: 0366-7022
Official Date: 5 August 2008
Dates:
DateEvent
5 August 2008Published
Volume: Vol.37
Number: No.8
Number of Pages: 2
Page Range: pp. 882-883
DOI: 10.1246/cl.2008.882
Status: Peer Reviewed
Publication Status: Published
Access rights to Published version: Restricted or Subscription Access

Data sourced from Thomson Reuters' Web of Knowledge

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