The Library
Asymmetric transfer hydrogenation of C=O and C=N bonds by tethered Rh-III catalysts
Tools
Tools
Tools
Matharu, Daljit S., Martins, Jose E. D. and Wills, Martin (2008) Asymmetric transfer hydrogenation of C=O and C=N bonds by tethered Rh-III catalysts. Chemistry - An Asian Journal, Vol.3 (No.8-9). pp. 1374-1383. doi:10.1002/asia.200800189
Research output not available from this repository, contact author.
Official URL: http://dx.doi.org/10.1002/asia.200800189
Abstract
Rh-III catalysts containing a tetramethylcyclopentadienyl group linked by a 'tether' to a tosylated diamine ligand have previously been reported by our group for the asymmetric transfer hydrogenation (ATH) of ketones. The extension of these catalysts to the asymmetric reduction of imines, as well as to more highly functionalized substrates is reported. In some cases, the catalysts give better ee values than other methods for these transformations at lower catalyst loadings. The introduction of a methoxy group into the tethering aryl ring does not negate the performance of the catalyst, thus opening up a route to supported derivatives.
| Item Type: | Journal Item | ||||
|---|---|---|---|---|---|
| Subjects: | Q Science > QD Chemistry | ||||
| Divisions: | Faculty of Science > Chemistry | ||||
| Journal or Publication Title: | Chemistry - An Asian Journal | ||||
| Publisher: | Wiley - V C H Verlag GmbH & Co. KGaA | ||||
| ISSN: | 1861-4728 | ||||
| Official Date: | 2008 | ||||
| Dates: |
|
||||
| Volume: | Vol.3 | ||||
| Number: | No.8-9 | ||||
| Number of Pages: | 10 | ||||
| Page Range: | pp. 1374-1383 | ||||
| DOI: | 10.1002/asia.200800189 | ||||
| Status: | Peer Reviewed | ||||
| Publication Status: | Published | ||||
| Funder: | Coordenacao de Aperfeicoamento de Pessoal de Ensinol Superior (CAPES, Brazil) |
Data sourced from Thomson Reuters' Web of Knowledge
Request changes or add full text files to a record
Repository staff actions (login required)
 |
View Item |
