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On the mechanism of charge transport in pentacene

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Laarhoven, H. A. v., Flipse, C. F. J., Koeberg, Mattijs, Bonn, M., Hendry, E., Orlandi, G., Jurchescu, O. D., Palstra, T. T. M. and Troisi, Alessandro (2008) On the mechanism of charge transport in pentacene. Journal of Chemical Physics, Vol.129 (No.4). article no. 044704 . doi:10.1063/1.2955462

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Official URL: http://dx.doi.org/10.1063/1.2955462

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Abstract

Terahertz transient conductivity measurements are performed on pentacene single crystals, which directly demonstrate a strong coupling of charge carriers to low frequency molecular motions with energies centered around 1.1 THz. We present evidence that the strong coupling to low frequency motions is the factor limiting the conductivity in these organic semiconductors. Our observations explain the apparent paradox of the "bandlike" temperature dependence of the conductivity beyond the validity limit of the band model. (C) 2008 American Institute of Physics.

Item Type: Journal Article
Subjects: Q Science > QC Physics
Q Science > QD Chemistry
Divisions: Faculty of Science > Chemistry
Faculty of Science > Centre for Scientific Computing
Library of Congress Subject Headings (LCSH): Charge transfer, Pentacene, Organic semiconductors
Journal or Publication Title: Journal of Chemical Physics
Publisher: American Institute of Physics
ISSN: 0021-9606
Official Date: 28 July 2008
Dates:
DateEvent
28 July 2008Published
Volume: Vol.129
Number: No.4
Number of Pages: 5
Page Range: article no. 044704
DOI: 10.1063/1.2955462
Status: Peer Reviewed
Publication Status: Published

Data sourced from Thomson Reuters' Web of Knowledge

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