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The first organic paramagnetic metal containing the aminoxyl radical
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Akutsu, Hiroki, Sato, K. (Keiko), Yamashita, S. (Shinji), Yamada, Jun-ichi, Nakatsuji, Shin'ichi and Turner, Scott S. (2008) The first organic paramagnetic metal containing the aminoxyl radical. Journal of Materials Chemistry, Vol.18 (No.28). pp. 3313-3315. doi:10.1039/b806694a ISSN 0959-9428.
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Official URL: http://dx.doi.org/10.1039/b806694a
Abstract
We have prepared an organic magnetic anion, PROXYL-4-CON-HCH2SO3- (1). The electrocrystallisation of BEDT-TTF with PPh(4)1 gave the first purely organic paramagnetic metal, beta ''(BEDT-TTF)(2)(1). The salt shows a broad metal-insulator transition at approximately 210 K.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QC Physics Q Science > QD Chemistry |
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Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||
Library of Congress Subject Headings (LCSH): | Paramagnetism, Anions, Radicals (Chemistry), Metal-insulator transitions | ||||
Journal or Publication Title: | Journal of Materials Chemistry | ||||
Publisher: | Royal Society of Chemistry | ||||
ISSN: | 0959-9428 | ||||
Official Date: | 2008 | ||||
Dates: |
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Volume: | Vol.18 | ||||
Number: | No.28 | ||||
Number of Pages: | 3 | ||||
Page Range: | pp. 3313-3315 | ||||
DOI: | 10.1039/b806694a | ||||
Status: | Peer Reviewed | ||||
Publication Status: | Published | ||||
Access rights to Published version: | Restricted or Subscription Access |
Data sourced from Thomson Reuters' Web of Knowledge
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