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Electron paramagnetic resonance studies of silicon-related defects in diamond
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Edmonds, A. M., Newton, Mark E., Martineau, P. M., Twitchen, D. J. and Williams, S. D. (2008) Electron paramagnetic resonance studies of silicon-related defects in diamond. Physical Review B (Condensed Matter and Materials Physics), Vol.77 (No.24). doi:10.1103/PhysRevB.77.245205 ISSN 1098-0121.
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Official URL: http://dx.doi.org/10.1103/PhysRevB.77.245205
Abstract
We report the results of multifrequency electron paramagnetic resonance studies at temperatures between 8 and 300 K on diamonds synthesized by chemical vapor deposition and intentionally silicon doped with isotopes in natural abundance or isotopically enriched. The Si-29 hyperfine structure has provided definitive evidence for the involvement of silicon in two electron paramagnetic resonance centers in diamond that were previously suspected to involve silicon: KUL1 and KUL3. We present data that unambiguously identify KUL1 as an S=1 neutral silicon split-vacancy (D-3d symmetry) defect (V-Si-V)(0), while KUL3 is shown to be (V-Si-V)(0) decorated with a hydrogen atom, (V-Si-V:H)(0).
| Item Type: | Journal Article | ||||
|---|---|---|---|---|---|
| Subjects: | Q Science > QC Physics T Technology > TS Manufactures |
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| Divisions: | Faculty of Science, Engineering and Medicine > Science > Physics | ||||
| Library of Congress Subject Headings (LCSH): | Electron paramagnetic resonance, Diamonds -- Defects, Chemical vapor deposition, Silicon | ||||
| Journal or Publication Title: | Physical Review B (Condensed Matter and Materials Physics) | ||||
| Publisher: | American Physical Society | ||||
| ISSN: | 1098-0121 | ||||
| Official Date: | June 2008 | ||||
| Dates: |
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| Volume: | Vol.77 | ||||
| Number: | No.24 | ||||
| Number of Pages: | 11 | ||||
| DOI: | 10.1103/PhysRevB.77.245205 | ||||
| Status: | Peer Reviewed | ||||
| Publication Status: | Published | ||||
| Access rights to Published version: | Restricted or Subscription Access | ||||
| Funder: | Engineering and Physical Sciences Research Council (EPSRC) | ||||
| Grant number: | GR/S96777/01 (EPSRC) |
Data sourced from Thomson Reuters' Web of Knowledge
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