Edmonds, A. M., Newton, Mark E., Martineau, P. M., Twitchen, D. J. and Williams, S. D.. (2008) Electron paramagnetic resonance studies of silicon-related defects in diamond. Physical Review B (Condensed Matter and Materials Physics), Vol.77 (No.24). ISSN 1098-0121

Full text not available from this repository.

Abstract

We report the results of multifrequency electron paramagnetic resonance studies at temperatures between 8 and 300 K on diamonds synthesized by chemical vapor deposition and intentionally silicon doped with isotopes in natural abundance or isotopically enriched. The Si-29 hyperfine structure has provided definitive evidence for the involvement of silicon in two electron paramagnetic resonance centers in diamond that were previously suspected to involve silicon: KUL1 and KUL3. We present data that unambiguously identify KUL1 as an S=1 neutral silicon split-vacancy (D-3d symmetry) defect (V-Si-V)(0), while KUL3 is shown to be (V-Si-V)(0) decorated with a hydrogen atom, (V-Si-V:H)(0).

[error in script] [error in script]

Item Type:	Journal Article
Subjects:	Q Science > QC Physics T Technology > TS Manufactures
Divisions:	Faculty of Science > Physics
Library of Congress Subject Headings (LCSH):	Electron paramagnetic resonance, Diamonds -- Defects, Chemical vapor deposition, Silicon
Journal or Publication Title:	Physical Review B (Condensed Matter and Materials Physics)
Publisher:	American Physical Society
ISSN:	1098-0121
Date:	June 2008
Volume:	Vol.77
Number:	No.24
Number of Pages:	11
Identification Number:	10.1103/PhysRevB.77.245205
Status:	Peer Reviewed
Publication Status:	Published
Access rights to Published version:	Restricted or Subscription Access
Funder:	Engineering and Physical Sciences Research Council (EPSRC)
Grant number:	GR/S96777/01 (EPSRC)
References:	J. Isberg, J. Hammersberg, E. Johansson, T. Wikstrom, D. J. Twitchen, A. J. Whitehead, S. E. Coe, and G. A. Scarsbrook, Science 297, 1670 �2002�. 2A. T. Collins, in Properties and Growth of Diamond, edited by G. Davies �INSPEC, London, 1994�, Chap. 9.7, p. 288. 3 J. W. Vandersande, in Properties and Growth of Diamond, edited by G. Davies �INSPEC, London, 1994�, Chap. 1.7, pp. 33–35. 4 J. Barjon, E. Rzepka, F. Jomard, J. M. Laroche, D. Ballutaud, T. Kociniewski, and J. Chevallier, Phys. Status Solidi A 202, 2177 �2005�. 5P. Joeris, I. Schmidt, and C. Benndorf, Diamond Relat. Mater. 5, 603 �1996�. 6V. S. Vavilov, A. A. Gippius, A. M. Zaitsev, B. V. Deryaguin, B. V. Spitsyn, and A. E. Aleksenko, Sov. Phys. Semicond. 14, 1078 �1980�. 7A. M. Zaitsev, V. S. Vavilov, and A. A. Gippius, Sov. Phys. Lebedev. Inst. Rep. 10, 15 �1981�. 8G. Sittas, H. Kanda, I. Kiflawi, and P. M. Spear, Diamond Relat. Mater. 5, 866 �1996�. 9C. D. Clark, H. Kanda, I. Kiflawi, and G. Sittas, Phys. Rev. B 51, 16681 �1995�. 10C. D. Clark and C. B. Dickerson, Surf. Coat. Technol. 47, 336 �1991�. 11A. T. Collins, L. Allers, C. J. H. Wort, and G. A. Scarsbrook, Diamond Relat. Mater. 3, 932 �1994�. 12G. Davies, S. C. Lawson, A. T. Collins, A. Mainwood, and S. J. Sharp, Phys. Rev. B 46, 13157 �1992�. 13 J. P. Goss, R. Jones, S. J. Breuer, P. R. Briddon, and S. Oberg, Phys. Rev. Lett. 77, 3041 �1996�. 14G. D. Watkins, Phys. Rev. B 12, 4383 �1975�. 15 J. P. Goss, P. R. Briddon, R. Jones, and S. Sque, Diamond Relat. Mater. 13, 684 �2004�. 16 J. P. Goss, P. R. Briddon, M. J. Rayson, S. J. Sque, and R. Jones, Phys. Rev. B 72, 035214 �2005�. 17A. T. Collins, M. Kamo, and Y. Sato, J. Mater. Res. 5, 2507 �1990�. 18 S. W. Brown and S. C. Rand, J. Appl. Phys. 78, 4069 �1995�. 19H. Sternschulte, K. Thonke, J. Gerster, W. Limmer, R. Sauer, J. Spitzer, and P. C. Munzinger, Diamond Relat. Mater. 4, 1189 �1995�. 20 J. P. Goss, P. R. Briddon, and M. J. Shaw, Phys. Rev. B 76, 075204 �2007�. 21C. L. Wang, C. Kurtsiefer, H. Weinfurter, and B. Burchard, J. Phys. B 39, 37 �2006�. 22K. Iakoubovskii and A. Stesmans, Phys. Status Solidi A 186, 199 �2001�. 23K. Iakoubovskii, A. Stesmans, K. Suzuki, J. Kuwabara, and A. Sawabe, Diamond Relat. Mater. 12, 511 �2003�. 24K. Iakoubovskii and A. Stesmans, Phys. Rev. B 66, 195207 �2002�. 25K. Iakoubovskii, A. Stesmans, M. Nesladek, and G. Knuyt, Phys. Status Solidi A 193, 448 �2002�. 26 S. D. Williams, D. J. Twitchen, P. M. Martineau, G. A. Scarsbrook, and I. Friel, UK Patent Application No. GB 2428690 A �pending�. 27D. J. Twitchen, M. E. Newton, J. M. Baker, O. D. Tucker, T. R. Anthony, and W. F. Banholzer, Phys. Rev. B 54, 6988 �1996�. 28D. F. Howarth, J. A. Weil, and Z. Zimpel, J. Magn. Reson. 161, 215 �2003�. 29 J. S. Hyde, M. Pasenkiewicz-Gierula, A. Jesmanowicz, and W. E. Antholine, Appl. Magn. Reson. 1, 483 �1990�. 30 S. C. Lawson, D. Fisher, D. C. Hunt, and M. E. Newton, J. Phys.: Condens. Matter 10, 6171 �1998�. 31R. M. Chrenko, H. M. Strong, and R. E. Tuft, Philos. Mag. 23, 313 �1971�. 32G. Davies, Physica B �Amsterdam� 273-274, 15 �1999�. 33G. Davies, Rep. Prog. Phys. 44, 787 �1981�. 34K. Iakoubovskii, G. J. Adriaenssens, N. N. Dogadkin, and A. A. Shiryaev, Diamond Relat. Mater. 10, 18 �2001�. 35W. V. Smith, P. P. Sorokin, I. L. Gelles, and G. J. Lasher, Phys. Rev. 115, 1546 �1959�. 36D. J. Twitchen, M. E. Newton, J. M. Baker, T. R. Anthony, and W. F. Banholzer, Phys. Rev. B 59, 12900 �1999�. 37 J. R. Morton and K. F. Preston, J. Magn. Reson. 30, 577 �1978�. 38D. R. Lide, CRC Handbook of Chemistry and Physics, 87th ed. �CRC, Boca Raton, FL, 2006�. 39A. Abragam, J. Horowitz, M. H. L. Pryce, and K. W. Morton, Proc. R. Soc. London, Ser. A 230, 169 �1955�. 40 J. H. Wood and G. W. Pratt, Phys. Rev. 107, 995 �1957�. 41M. Gerloch, Orbitals, Terms and States �Wiley, Chichester, 1986�. 42 S. Felton, A. M. Edmonds, M. E. Newton, P. M. Martineau, D. Fisher, and D. J. Twitchen, Phys. Rev. B 77, 081201�R� �2008�
URI:	http://wrap.warwick.ac.uk/id/eprint/29741

Data sourced from Thomson Reuters' Web of Knowledge

Request changes to a record

Actions (login required)

View Item