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Synthesis of a series of novel N,N-dialkyl-TsDPEN ligands and their application to enantioselective addition of dialkylzinc to benzaldehyde
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Martins, Jose E. D. and Wills, Martin (2008) Synthesis of a series of novel N,N-dialkyl-TsDPEN ligands and their application to enantioselective addition of dialkylzinc to benzaldehyde. Tetrahedron: Asymmetry, Vol.19 (No.10). pp. 1250-1255. doi:10.1016/j.tetasy.2008.04.020
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Official URL: http://dx.doi.org/10.1016/j.tetasy.2008.04.020
Abstract
A series of mono- and dialkylated derivatives of C2-symmetric N-tosyl-1,2-diphenylethylene diamines have been prepared and used as ligands for the enantiomeric control of the addition of diethylzinc to aldehydes. Addition products of up to 79% ee were formed. (C) 2008 Elsevier Ltd. All rights reserved.
| Item Type: | Journal Article | ||||
|---|---|---|---|---|---|
| Subjects: | Q Science > QD Chemistry | ||||
| Divisions: | Faculty of Science > Chemistry | ||||
| Library of Congress Subject Headings (LCSH): | Ligands, Biosynthesis, Enantioselective catalysis, Benzaldehyde | ||||
| Journal or Publication Title: | Tetrahedron: Asymmetry | ||||
| Publisher: | Pergamon | ||||
| ISSN: | 0957-4166 | ||||
| Official Date: | 30 May 2008 | ||||
| Dates: |
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| Volume: | Vol.19 | ||||
| Number: | No.10 | ||||
| Number of Pages: | 6 | ||||
| Page Range: | pp. 1250-1255 | ||||
| DOI: | 10.1016/j.tetasy.2008.04.020 | ||||
| Status: | Peer Reviewed | ||||
| Publication Status: | Published | ||||
| Funder: | Brazil. Coordenação do Aperfeiçoamento de Pessoal de Nível Superior (CAPES) |
Data sourced from Thomson Reuters' Web of Knowledge
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