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Synthesis of a series of novel N,N-dialkyl-TsDPEN ligands and their application to enantioselective addition of dialkylzinc to benzaldehyde

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Martins, Jose E. D. and Wills, Martin (2008) Synthesis of a series of novel N,N-dialkyl-TsDPEN ligands and their application to enantioselective addition of dialkylzinc to benzaldehyde. Tetrahedron: Asymmetry, Vol.19 (No.10). pp. 1250-1255. doi:10.1016/j.tetasy.2008.04.020

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Official URL: http://dx.doi.org/10.1016/j.tetasy.2008.04.020

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Abstract

A series of mono- and dialkylated derivatives of C2-symmetric N-tosyl-1,2-diphenylethylene diamines have been prepared and used as ligands for the enantiomeric control of the addition of diethylzinc to aldehydes. Addition products of up to 79% ee were formed. (C) 2008 Elsevier Ltd. All rights reserved.

Item Type: Journal Article
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science > Chemistry
Library of Congress Subject Headings (LCSH): Ligands, Biosynthesis, Enantioselective catalysis, Benzaldehyde
Journal or Publication Title: Tetrahedron: Asymmetry
Publisher: Pergamon
ISSN: 0957-4166
Official Date: 30 May 2008
Dates:
DateEvent
30 May 2008Published
Volume: Vol.19
Number: No.10
Number of Pages: 6
Page Range: pp. 1250-1255
DOI: 10.1016/j.tetasy.2008.04.020
Status: Peer Reviewed
Publication Status: Published
Funder: Brazil. Coordenação do Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Data sourced from Thomson Reuters' Web of Knowledge

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