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Quantitative measurement of Q(3) species in silicate and borosilicate glasses using Raman spectroscopy

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Parkinson, B. G., Holland, D., Smith, Mark E., Larson, C., Doerr, J., Affatigato, Mario, Feller, Steven A., Howes, A. P. and Scales, C. R.. (2008) Quantitative measurement of Q(3) species in silicate and borosilicate glasses using Raman spectroscopy. Journal of Non-Crystalline Solids, Vol.354 (No.17). pp. 1936-1942. ISSN 0022-3093

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Abstract

Raman spectroscopy has been used to measure the fraction of tetrahedral silicate units connected at three corners into the network (Q(3)) in binary lithium silicate glasses and also in the more complex borosilicate glasses used for waste immobilization. Agreement within experimental error was obtained with Si-29 MAS NMR measurements of the same samples. Raman provides an alternative method of structural determination for silicon-containing glasses with a high content of paramagnetic species where NMR loses resolution. Analysis was performed on borosilicate glasses containing up to 11.98 mol% Fe2O3 and the Q(3) values obtained by Raman spectroscopy agree within error with the published Si-29 NMR results from borosilicate glasses containing the equivalent quantity of Al2O3. (C) 2007 Elsevier B.V. All rights reserved.

Item Type: Journal Article
Subjects: Q Science > QC Physics
T Technology > TP Chemical technology
Divisions: Administration > Vice Chancellor's Office
Faculty of Science > Physics
Library of Congress Subject Headings (LCSH): Raman spectroscopy, Glass, Silicates, Hazardous wastes, Nuclear magnetic resonance spectroscopy, Chemistry, Analytic -- Quantitative
Journal or Publication Title: Journal of Non-Crystalline Solids
Publisher: Elsevier Science BV
ISSN: 0022-3093
Official Date: 1 April 2008
Volume: Vol.354
Number: No.17
Number of Pages: 7
Page Range: pp. 1936-1942
Identification Number: 10.1016/j.jnoncrysol.2007.06.105
Status: Peer Reviewed
Publication Status: Published
Access rights to Published version: Restricted or Subscription Access
Funder: Engineering and Physical Sciences Research Council (EPSRC), Nexia Solutions Limited
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URI: http://wrap.warwick.ac.uk/id/eprint/29833

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