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Quantitative measurement of Q(3) species in silicate and borosilicate glasses using Raman spectroscopy

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Parkinson, B. G., Holland, D., Smith, Mark E., Larson, C., Doerr, J., Affatigato, Mario, Feller, Steven A., Howes, A. P. and Scales, C. R.. (2008) Quantitative measurement of Q(3) species in silicate and borosilicate glasses using Raman spectroscopy. Journal of Non-Crystalline Solids, Vol.354 (No.17). pp. 1936-1942. ISSN 0022-3093

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Official URL: http://dx.doi.org/10.1016/j.jnoncrysol.2007.06.105

Abstract

Raman spectroscopy has been used to measure the fraction of tetrahedral silicate units connected at three corners into the network (Q(3)) in binary lithium silicate glasses and also in the more complex borosilicate glasses used for waste immobilization. Agreement within experimental error was obtained with Si-29 MAS NMR measurements of the same samples. Raman provides an alternative method of structural determination for silicon-containing glasses with a high content of paramagnetic species where NMR loses resolution. Analysis was performed on borosilicate glasses containing up to 11.98 mol% Fe2O3 and the Q(3) values obtained by Raman spectroscopy agree within error with the published Si-29 NMR results from borosilicate glasses containing the equivalent quantity of Al2O3. (C) 2007 Elsevier B.V. All rights reserved.

Item Type:

Journal Article

Subjects:

Q Science > QC Physics
T Technology > TP Chemical technology

Divisions:

Administration > Vice Chancellor's Office
Faculty of Science > Physics

Library of Congress Subject Headings (LCSH):

Raman spectroscopy, Glass, Silicates, Hazardous wastes, Nuclear magnetic resonance spectroscopy, Chemistry, Analytic -- Quantitative

Journal or Publication Title:

Journal of Non-Crystalline Solids

Publisher:

Elsevier Science BV

ISSN:

0022-3093

Official Date:

1 April 2008

Dates:

Date	Event
1 April 2008	Published

Volume:

Vol.354

Number:

No.17

Number of Pages:

Page Range:

pp. 1936-1942

Identification Number:

10.1016/j.jnoncrysol.2007.06.105

Status:

Peer Reviewed

Publication Status:

Published

Access rights to Published version:

Restricted or Subscription Access

Funder:

Engineering and Physical Sciences Research Council (EPSRC), Nexia Solutions Limited

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