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Estimation of internuclear couplings in the solid-state NMR of multiple-spin systems. Selective spin echoes and off-magic-angle sample spinning
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Pileio, Giuseppe, Mamone, S. (Salvatore), Mollica, Giulia, Montesinos, Ildefonso Marin, Gansmueller, Axel, Carravetta, Marina, Brown, Steven P. and Levitt, Malcolm H. (2008) Estimation of internuclear couplings in the solid-state NMR of multiple-spin systems. Selective spin echoes and off-magic-angle sample spinning. Chemical Physics Letters, Vol.456 (No.1-3). pp. 116-121. doi:10.1016/j.cplett.2008.03.021
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Official URL: http://dx.doi.org/10.1016/j.cplett.2008.03.021
Abstract
Internuclear couplings between selected homonuclear spin pairs in a multiply-labelled spin system are determined by NMR spin echo experiments in the solid-state. The spin echoes are induced by an amplitude-modulated shaped pulse. The time shift in the echo modulation curve is treated by average Hamiltonian theory and verified by numerical simulation. The J-couplings may be estimated by experiments on samples spinning at the magic-angle, while the direct dipole-dipole couplings may be estimated by off-magic-angle spinning. The concept is tested on a uniformly C-13-enriched sample of L-histidine hydrochloride monohydrate. (C) 2008 Elsevier B.V. All rights reserved.
| Item Type: | Journal Article | ||||
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| Subjects: | Q Science > QD Chemistry Q Science > QC Physics |
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| Divisions: | Faculty of Science > Physics | ||||
| Library of Congress Subject Headings (LCSH): | Nuclear magnetic resonance spectroscopy, Nuclear spin | ||||
| Journal or Publication Title: | Chemical Physics Letters | ||||
| Publisher: | Elsevier BV | ||||
| ISSN: | 0009-2614 | ||||
| Official Date: | 21 April 2008 | ||||
| Dates: |
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| Volume: | Vol.456 | ||||
| Number: | No.1-3 | ||||
| Number of Pages: | 6 | ||||
| Page Range: | pp. 116-121 | ||||
| DOI: | 10.1016/j.cplett.2008.03.021 | ||||
| Status: | Peer Reviewed | ||||
| Publication Status: | Published | ||||
| Access rights to Published version: | Restricted or Subscription Access | ||||
| Funder: | Engineering and Physical Sciences Research Council (EPSRC) |
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