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Metal and ligand control of sulfenate reactivity : arene ruthenium thiolato-mono-S-oxides

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Petzold, Holm, Xu, Jingjing and Sadler, P. J.. (2008) Metal and ligand control of sulfenate reactivity : arene ruthenium thiolato-mono-S-oxides. Angewandte Chemie International Edition, Vol.47 (No.16). pp. 3008-3011. ISSN 1433-7851

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Official URL: http://dx.doi.org/10.1002/anie.200705342

Abstract

Going OS: Oxygenation of thiolate sulfur atoms can control biological signaling processes. Rare examples of a monodentate sulfenate ligands stabilized by hydrogen bonding to a diamine ligand within organometallic ruthenium arene complexes of pharmaceutical interest and their unusual acid/base properties are reported.

Item Type: Journal Article
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science > Chemistry
Library of Congress Subject Headings (LCSH): Antineoplastic agents -- Development, Ruthenium compounds, Oxidation, Sulfonates, Ligands
Journal or Publication Title: Angewandte Chemie International Edition
Publisher: Wiley - V C H Verlag GmbH & Co. KGaA
ISSN: 1433-7851
Date: 7 April 2008
Volume: Vol.47
Number: No.16
Number of Pages: 4
Page Range: pp. 3008-3011
Identification Number: 10.1002/anie.200705342
Status: Peer Reviewed
Publication Status: Published
Access rights to Published version: Restricted or Subscription Access
Funder: Deutscher Akademischer Austauschdienst (DAAD), ORS, Research Councils UK (RCUK)
Grant number: D/06/45748 (DAAD)
URI: http://wrap.warwick.ac.uk/id/eprint/30245

Data sourced from Thomson Reuters' Web of Knowledge

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