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Vibrational predissociation in weakly-bound clusters: A dispersed fluorescence study of toluene rare-gas complexes

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Da Campo, Raffaello and Mackenzie, Stuart R. (2008) Vibrational predissociation in weakly-bound clusters: A dispersed fluorescence study of toluene rare-gas complexes. Chemical Physics Letters, Volume 452 (Numbers 1-3). pp. 6-13. doi:10.1016/j.cplett.2007.12.020 ISSN 0009-2614.

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Official URL: http://dx.doi.org/10.1016/j.cplett.2007.12.020

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Abstract

The vibrational predissociation (VP) dynamics of toluene-Ar and toluene-Ne complexes have been investigated using single vibronic level fluorescence spectroscopy. For several levels, comparison of the dispersed fluorescence spectra wit those from monomer levels permits the identification of the final monomer vibrational level. Pumping of the low-lying S-1 13(0)(1)/24(0)(1)/25(0)(1) or 37(0)(1) transitions in toluene-Ar, for example, gives rise to efficient VP leaving the resulting toluene monomer in its vibrationless S-1 state. By contrast, in the case of toluene-Ne, VP following 37(1) level pumping leaves the toluene molecule in an excited 16(1) level which is optically inaccessible from the ground state. (c) 2007 Elsevier B.V. All rights reserved.

Item Type: Journal Article
Subjects: Q Science > QD Chemistry
Q Science > QC Physics
Divisions: Faculty of Science, Engineering and Medicine > Science > Chemistry
Library of Congress Subject Headings (LCSH): Fluorescence spectroscopy, Toluene -- Spectra, Complex compounds -- Spectra, Microclusters
Journal or Publication Title: Chemical Physics Letters
Publisher: Elsevier BV
ISSN: 0009-2614
Official Date: 4 February 2008
Dates:
DateEvent
4 February 2008Published
Volume: Volume 452
Number: Numbers 1-3
Number of Pages: 8
Page Range: pp. 6-13
DOI: 10.1016/j.cplett.2007.12.020
Status: Peer Reviewed
Publication Status: Published
Access rights to Published version: Restricted or Subscription Access

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