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(1R,2R)-4-Benzoyl-2-benzoyloxy-1-phenylbutyl imidazole-1-carboxylate
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Fox, David J., Parris, Sean, Pedersen, Daniel Sejer and Warren, Stuart (2008) (1R,2R)-4-Benzoyl-2-benzoyloxy-1-phenylbutyl imidazole-1-carboxylate. Acta Crystallographica. Section E: Structure Reports Online, Vol.64 (Part 3). O619-U1385. doi:10.1107/S1600536808004364
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Official URL: http://dx.doi.org/10.1107/S1600536808004364
Abstract
The title compound, C28H24N2O5, was prepared from (E)-2cinnamyl-1,3-diphenylpropane-1,3-dione using standard Sharpless asymmetric dihydroxylation conditions, followed by treatment with 1,1'-carbonyl diimidazole. In the crystal structure, the phenyl rings form intermolecular face-to-face pi-pi contacts, with an interplanar angle of 15.5 ( 2) and a centroid-centroid distance of 4.73 (1) angstrom. One phenyl ring also forms a C-H center dot center dot center dot pi contact to an adjacent imidazole ring, with an H center dot center dot center dot centroid distance of 3.18 angstrom.
| Item Type: | Journal Article | ||||
|---|---|---|---|---|---|
| Subjects: | Q Science > QD Chemistry | ||||
| Divisions: | Faculty of Science > Chemistry | ||||
| Journal or Publication Title: | Acta Crystallographica. Section E: Structure Reports Online | ||||
| Publisher: | Wiley-Blackwell Publishing, Inc. | ||||
| ISSN: | 1600-5368 | ||||
| Official Date: | March 2008 | ||||
| Dates: |
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| Volume: | Vol.64 | ||||
| Number: | Part 3 | ||||
| Number of Pages: | 12 | ||||
| Page Range: | O619-U1385 | ||||
| DOI: | 10.1107/S1600536808004364 | ||||
| Status: | Peer Reviewed | ||||
| Publication Status: | Published | ||||
| Access rights to Published version: | Restricted or Subscription Access |
Data sourced from Thomson Reuters' Web of Knowledge
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