Skip to content Skip to navigation
University of Warwick
  • Study
  • |
  • Research
  • |
  • Business
  • |
  • Alumni
  • |
  • News
  • |
  • About

University of Warwick
Publications service & WRAP

Highlight your research

  • WRAP
    • Home
    • Search WRAP
    • Browse by Warwick Author
    • Browse WRAP by Year
    • Browse WRAP by Subject
    • Browse WRAP by Department
    • Browse WRAP by Funder
    • Browse Theses by Department
  • Publications Service
    • Home
    • Search Publications Service
    • Browse by Warwick Author
    • Browse Publications service by Year
    • Browse Publications service by Subject
    • Browse Publications service by Department
    • Browse Publications service by Funder
  • Help & Advice
University of Warwick

The Library

  • Login
  • Admin

The determination of O-17 NMR parameters of hydroxyl oxygen : a combined deuteration and DOR approach

Tools
- Tools
+ Tools

Wong, Alan, Hung, Ivan, Howes, Andy P., Anupõld, Tiit, Past, Jaan, Samoson, Ago, Brown, Steven P., Smith, Mark E. and Dupree, Ray (2007) The determination of O-17 NMR parameters of hydroxyl oxygen : a combined deuteration and DOR approach. Magnetic Resonance in Chemistry, Vol.45 (Suppl.S). S68-S72. doi:10.1002/mrc.2088

Research output not available from this repository, contact author.
Official URL: http://dx.doi.org/10.1002/mrc.2088

Request Changes to record.

Abstract

The direct detection of hydroxyl oxygen (O-H) by O-17 double-rotation (DOR) NMR is very challenging because of the strong O-H dipole interaction. It is shown that deuteration of the hydroxyl site overcomes this using glycine-HCl as an illustration. Two well-separated sets of narrow (linewidth similar to 80-100 Hz) resonances with their spinning-sidebands are observed for the carboxyl and hydroxyl oxygens in the DOR spectrum of [O-17,H-2]glycine center dot HCl. The chemical shift anisotropy of these sites is obtained from a simulation of the DOR spinning-sideband intensities. The chemical shift span (Omega) for the carboxyl oxygen is found to be much larger than that of the hydroxyl oxygen, with Omega values of 540 +/- 15 and 210 +/- 10 ppm, respectively.

Item Type: Journal Article
Subjects: Q Science > QD Chemistry
Q Science > QC Physics
Divisions: Administration > Vice Chancellor's Office
Faculty of Science > Physics
Journal or Publication Title: Magnetic Resonance in Chemistry
Publisher: John Wiley & Sons Ltd.
ISSN: 0749-1581
Official Date: December 2007
Dates:
DateEvent
December 2007Published
Volume: Vol.45
Number: Suppl.S
Number of Pages: 5
Page Range: S68-S72
DOI: 10.1002/mrc.2088
Status: Peer Reviewed
Publication Status: Published
Access rights to Published version: Restricted or Subscription Access

Data sourced from Thomson Reuters' Web of Knowledge

Request changes or add full text files to a record

Repository staff actions (login required)

View Item View Item
twitter

Email us: wrap@warwick.ac.uk
Contact Details
About Us