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Umbrella motion in aziridines: use of simple chemical inputs to reversibly control the rate of pyramidal inversion
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Davies, Mark W., Clarke, Adam J., Clarkson, Guy J., Shipman, Michael and Tucker, James H. R.. (2007) Umbrella motion in aziridines: use of simple chemical inputs to reversibly control the rate of pyramidal inversion. CHEMICAL COMMUNICATIONS (47). pp. 5078-5080. ISSN 1359-7345
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Official URL: http://dx.doi.org/10.1039/b712447c
Abstract
The molecular motion associated with atomic inversion at an aziridine nitrogen can be essentially halted by metal complexation; addition of a second chemical input that decomplexes the metal from the aziridine restores fast inversion (k = 40 s(-1) at 303 K).
| Item Type: | Journal Article |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Journal or Publication Title: | CHEMICAL COMMUNICATIONS |
| Publisher: | ROYAL SOC CHEMISTRY |
| ISSN: | 1359-7345 |
| Date: | 2007 |
| Number: | 47 |
| Number of Pages: | 3 |
| Page Range: | pp. 5078-5080 |
| Identification Number: | 10.1039/b712447c |
| Publication Status: | Published |
| URI: | http://wrap.warwick.ac.uk/id/eprint/30943 |
Data sourced from Thomson Reuters' Web of Knowledge
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