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Umbrella motion in aziridines : use of simple chemical inputs to reversibly control the rate of pyramidal inversion
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Davies, Mark W., Clarke, Adam J., Clarkson, Guy J., Shipman, Michael and Tucker, James H. R. (2007) Umbrella motion in aziridines : use of simple chemical inputs to reversibly control the rate of pyramidal inversion. Chemical Communications (Number 47). pp. 5078-5080. doi:10.1039/b712447c ISSN 1359-7345.
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Official URL: http://dx.doi.org/10.1039/b712447c
Abstract
The molecular motion associated with atomic inversion at an aziridine nitrogen can be essentially halted by metal complexation; addition of a second chemical input that decomplexes the metal from the aziridine restores fast inversion (k = 40 s(-1) at 303 K).
| Item Type: | Journal Article | ||||
|---|---|---|---|---|---|
| Subjects: | Q Science > QD Chemistry | ||||
| Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||
| Journal or Publication Title: | Chemical Communications | ||||
| Publisher: | Royal Society of Chemistry | ||||
| ISSN: | 1359-7345 | ||||
| Official Date: | 2007 | ||||
| Dates: |
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| Number: | Number 47 | ||||
| Number of Pages: | 3 | ||||
| Page Range: | pp. 5078-5080 | ||||
| DOI: | 10.1039/b712447c | ||||
| Status: | Peer Reviewed | ||||
| Publication Status: | Published | ||||
| Access rights to Published version: | Restricted or Subscription Access |
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