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An anionic weak acceptor 2-aminomethylsulfo-3,5,6-trichloro-1, 4-benzoquinone and its BEDT-TTF-based charge-transfer salts
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Akutsu, Hiroki, Yamada, Jun-ichi, Nakatsuji, Shin'ichi and Turner, Scott S. (2007) An anionic weak acceptor 2-aminomethylsulfo-3,5,6-trichloro-1, 4-benzoquinone and its BEDT-TTF-based charge-transfer salts. Solid State Communications, Vol.144 (No.3-4). pp. 144-147. doi:10.1016/j.ssc.2007.07.034 ISSN 0038-1098.
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Official URL: http://dx.doi.org/10.1016/j.ssc.2007.07.034
Abstract
We have prepared a novel organic anionic weak acceptors 2-aminomethylsulfo-3,5,6-trichloro-1,4-benzoquinone (1), as a PPh4 salt. Cyclic voltammetry indicates that its reduction potential is 0.53 V lower than that of chloranil. Electrocrystallisation with BEDT-TTF cave two salts. beta-beta-(BEDT-TTF)(2)(1)-0.5H(2)O (2) and beta"-(BEDT-TTF)(2)(1).CH3OH (3). Their crystal structures and physical properties are reported.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QC Physics | ||||
Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||
Journal or Publication Title: | Solid State Communications | ||||
Publisher: | Pergamon | ||||
ISSN: | 0038-1098 | ||||
Official Date: | October 2007 | ||||
Dates: |
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Volume: | Vol.144 | ||||
Number: | No.3-4 | ||||
Number of Pages: | 4 | ||||
Page Range: | pp. 144-147 | ||||
DOI: | 10.1016/j.ssc.2007.07.034 | ||||
Status: | Peer Reviewed | ||||
Publication Status: | Published |
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