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Novel bis(ethylenedithio)tetrathiafulvalene-based organic conductor with 1,1 '-ferrocenedisulfonate
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Akutsu, Hiroki, Ohnishi, Ryo, Yamada, Jun-ich, Nakatsuji, Shin'ichi and Turner, Scott S. (2007) Novel bis(ethylenedithio)tetrathiafulvalene-based organic conductor with 1,1 '-ferrocenedisulfonate. Inorganic Chemistry, Vol.46 (No.21). pp. 8472-8474. doi:10.1021/ic701392z ISSN 0020-1669.
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Official URL: http://dx.doi.org/10.1021/ic701392z
Abstract
A new bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF)-based salt with a ferrocenyl moiety, alpha'''-(BEDT-TTF)(4)(Fe(C5H4SO3)(2))center dot 6H(2)O, has been prepared. The ferrocenyl part of this salt is neutral and diamagnetic, but the magnetic susceptibility is well modeled by a Curie-Weiss law with C = 0.142 emu center dot K center dot mol(-1) (approximate to 1/3 of S = 1/2 spin). The spin is likely to be localized on the donor layer because of its unique charge disproportionation.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||
Journal or Publication Title: | Inorganic Chemistry | ||||
Publisher: | American Chemical Society | ||||
ISSN: | 0020-1669 | ||||
Official Date: | 15 October 2007 | ||||
Dates: |
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Volume: | Vol.46 | ||||
Number: | No.21 | ||||
Number of Pages: | 3 | ||||
Page Range: | pp. 8472-8474 | ||||
DOI: | 10.1021/ic701392z | ||||
Status: | Peer Reviewed | ||||
Publication Status: | Published | ||||
Access rights to Published version: | Restricted or Subscription Access |
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