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Dynamics of H-loss in adenine via the (1)pi sigma* state using a combination of ns and fs laser spectroscopy
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Wells, Kym Lewis, Roberts, Gareth M. and Stavros, Vasilios G. (2007) Dynamics of H-loss in adenine via the (1)pi sigma* state using a combination of ns and fs laser spectroscopy. Chemical Physics Letters, Vol.446 (No.1-3). pp. 20-24. doi:10.1016/j.cplett.2007.08.040 ISSN 0009-2614.
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Official URL: http://dx.doi.org/10.1016/j.cplett.2007.08.040
Abstract
One of the key questions underlying adenine's photochemistry following 266 nm excitation is whether or not the dissociative (1)pi sigma* state plays an active role in the ensuing dynamics. This work describes how laser fluence studies on the Ad(+) and H+ following photo-excitation using a combination of ns and fs UY pulses with time-of-flight mass-spectrometry, provides new evidence that implicates the contentious participation of the (1)pi sigma* state in the photochemistry of adenine. (C) 2007 Elsevier B.V. All rights reserved.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||
Library of Congress Subject Headings (LCSH): | Photochemistry, Adenine, Laser spectroscopy, Elimination reactions | ||||
Journal or Publication Title: | Chemical Physics Letters | ||||
Publisher: | Elsevier BV | ||||
ISSN: | 0009-2614 | ||||
Official Date: | 26 September 2007 | ||||
Dates: |
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Volume: | Vol.446 | ||||
Number: | No.1-3 | ||||
Number of Pages: | 5 | ||||
Page Range: | pp. 20-24 | ||||
DOI: | 10.1016/j.cplett.2007.08.040 | ||||
Status: | Peer Reviewed | ||||
Publication Status: | Published | ||||
Funder: | Engineering and Physical Sciences Research Council (EPSRC), Royal Society (Great Britain) |
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