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Gas-phase methylation of [60]Fullerene
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Vieira, S. M. C., Drewello, T., Kotsiris, S. G., Rego, C. A. and Birkett, P. R.. (2007) Gas-phase methylation of [60]Fullerene. Journal of Physical Chemistry B, Vol.111 (No.35). pp. 10352-10356. ISSN 1520-6106
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Official URL: http://dx.doi.org/10.1021/jp0733623
Abstract
Direct methylation of [60]fullerene via a gas-phase reaction in a CH4/H-2 atmosphere was performed using a modified hot filament chemical vapor deposition method. Pressures were varied from 10 to 60 mbar and the substrate was maintained at 690 degrees C. High-resolution matrix-assisted laser desorption ionization (MALDI) mass spectrometry analysis showed signals corresponding to C60H18-2n(H,CH3)(n). Collision-induced dissociation experiments confirmed a maximum of 18 ligands possible to the [60]fullerene cage.
| Item Type: | Journal Article |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Divisions: | Faculty of Science > Chemistry |
| Journal or Publication Title: | Journal of Physical Chemistry B |
| Publisher: | American Chemical Society |
| ISSN: | 1520-6106 |
| Date: | 6 September 2007 |
| Volume: | Vol.111 |
| Number: | No.35 |
| Number of Pages: | 5 |
| Page Range: | pp. 10352-10356 |
| Identification Number: | 10.1021/jp0733623 |
| Status: | Peer Reviewed |
| Publication Status: | Published |
| Access rights to Published version: | Restricted or Subscription Access |
| URI: | http://wrap.warwick.ac.uk/id/eprint/31512 |
Data sourced from Thomson Reuters' Web of Knowledge
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