Newman, Christopher P., Casey-Green, Katherine, Clarkson, Guy J., Cave, Gareth W. V., Errington, W. and Rourke, Jonathan (2007) Cyclometallated platinum(II) complexes : oxidation to, and C-H activation by, platinum(IV). Dalton Transactions (Number 29). pp. 3170-3182. doi:10.1039/b705609e ISSN 1477-9226.

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Abstract

A series of cyclometallated phenylpyridine platinum(II) complexes have been synthesised with a systematic variation in both the phenylpyridine and the ancillary ligand. Oxidation of one of the cyclometallated species leads to a number of isomeric platinum(IV) complexes, all of which eventually isomerise to a single compound. The route to these new compounds has been demonstrated to involve an initial slow oxidation followed by a rapid C-H activation to give doubly cyclometallated complexes. The solid state structures of a number of both the platinum( II) and the platinum(IV) species have been solved; many of the structures exhibited extended interactions that result in complex three dimensional packing.

Item Type:	Journal Article
Subjects:	Q Science > QD Chemistry
Divisions:	Faculty of Science, Engineering and Medicine > Science > Chemistry
Journal or Publication Title:	Dalton Transactions
Publisher:	Royal Society of Chemistry
ISSN:	1477-9226
Official Date:	2007
Dates:	Date Event 2007 UNSPECIFIED
Number:	Number 29
Number of Pages:	13
Page Range:	pp. 3170-3182
DOI:	10.1039/b705609e
Status:	Peer Reviewed
Publication Status:	Published

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