
The Library
Cyclometallated platinum(II) complexes : oxidation to, and C-H activation by, platinum(IV)
Tools
Newman, Christopher P., Casey-Green, Katherine, Clarkson, Guy J., Cave, Gareth W. V., Errington, W. and Rourke, Jonathan (2007) Cyclometallated platinum(II) complexes : oxidation to, and C-H activation by, platinum(IV). Dalton Transactions (Number 29). pp. 3170-3182. doi:10.1039/b705609e ISSN 1477-9226.
Research output not available from this repository.
Request-a-Copy directly from author or use local Library Get it For Me service.
Official URL: http://dx.doi.org/10.1039/b705609e
Abstract
A series of cyclometallated phenylpyridine platinum(II) complexes have been synthesised with a systematic variation in both the phenylpyridine and the ancillary ligand. Oxidation of one of the cyclometallated species leads to a number of isomeric platinum(IV) complexes, all of which eventually isomerise to a single compound. The route to these new compounds has been demonstrated to involve an initial slow oxidation followed by a rapid C-H activation to give doubly cyclometallated complexes. The solid state structures of a number of both the platinum( II) and the platinum(IV) species have been solved; many of the structures exhibited extended interactions that result in complex three dimensional packing.
Item Type: | Journal Article | ||||
---|---|---|---|---|---|
Subjects: | Q Science > QD Chemistry | ||||
Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||
Journal or Publication Title: | Dalton Transactions | ||||
Publisher: | Royal Society of Chemistry | ||||
ISSN: | 1477-9226 | ||||
Official Date: | 2007 | ||||
Dates: |
|
||||
Number: | Number 29 | ||||
Number of Pages: | 13 | ||||
Page Range: | pp. 3170-3182 | ||||
DOI: | 10.1039/b705609e | ||||
Status: | Peer Reviewed | ||||
Publication Status: | Published |
Data sourced from Thomson Reuters' Web of Knowledge
Request changes or add full text files to a record
Repository staff actions (login required)
![]() |
View Item |