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Ru(II) complexes of cyclohexane diamine and monodentate phosphorus ligands for asymmetric ketone hydrogenation
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Xu, Yingjian (Andy), Docherty, Gordon, Woodward, Gary and Wills, Martin (2006) Ru(II) complexes of cyclohexane diamine and monodentate phosphorus ligands for asymmetric ketone hydrogenation. TETRAHEDRON-ASYMMETRY, 17 (20). pp. 2925-2929. doi:10.1016/j.tetasy.2006.10.036 ISSN 0957-4166.
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Official URL: http://dx.doi.org/10.1016/j.tetasy.2006.10.036
Abstract
The incorporation of a trans-1,2-diaminocyclohexane in place of DPEN provides improvements in enantioselectivity to asymmetric ketone hydrogenation reactions using BrXuPHOS-Ru-diamine catalysts. Substrates containing halogenated aryl rings are particularly compatible with this catalyst, however, alpha-chlorinated ketones remain resistant to reduction under any conditions. (c) 2006 Elsevier Ltd. All rights reserved.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | TETRAHEDRON-ASYMMETRY | ||||
Publisher: | PERGAMON-ELSEVIER SCIENCE LTD | ||||
ISSN: | 0957-4166 | ||||
Official Date: | 6 November 2006 | ||||
Dates: |
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Volume: | 17 | ||||
Number: | 20 | ||||
Number of Pages: | 5 | ||||
Page Range: | pp. 2925-2929 | ||||
DOI: | 10.1016/j.tetasy.2006.10.036 | ||||
Publication Status: | Published |
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