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Concise enantioselective synthesis of abscisic acid and a new analogue
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Smith, Timothy R., Clark, Andrew J., Clarkson, Guy J., Taylor, Paul C. and Marsh, Andrew (2006) Concise enantioselective synthesis of abscisic acid and a new analogue. Organic & biomolecular chemistry, 4 (22). pp. 4186-4192. doi:10.1039/b611880a ISSN 1477-0520.
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Official URL: http://dx.doi.org/10.1039/b611880a
Abstract
Short and high-yielding syntheses of enantiomerically pure (S)-(+) and (R)-(-)- abscisic acid are described. The syntheses proceed through key intermediates that preferentially recrystallise as single diastereoisomers for each enantiomer. This route allows the preparation of either enantiomer of abscisic acid in ca. 30% overall yield, and as demonstrated, gives access to an enantiomerically pure abscisic acid analogue.
| Item Type: | Journal Article | ||||
|---|---|---|---|---|---|
| Subjects: | Q Science > QD Chemistry | ||||
| Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||
| Journal or Publication Title: | Organic & biomolecular chemistry | ||||
| Publisher: | Royal Society of Chemistry | ||||
| ISSN: | 1477-0520 | ||||
| Official Date: | 2006 | ||||
| Dates: |
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| Volume: | 4 | ||||
| Number: | 22 | ||||
| Number of Pages: | 7 | ||||
| Page Range: | pp. 4186-4192 | ||||
| DOI: | 10.1039/b611880a | ||||
| Status: | Peer Reviewed | ||||
| Publication Status: | Published |
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