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Initial growth of platinum on oxygen-covered Ni(110) surfaces

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Walker, M., Parkinson, C. R., Draxler, M., Brown, M. G. and McConville, C. F.. (2006) Initial growth of platinum on oxygen-covered Ni(110) surfaces. Surface Science, 600 (16). pp. 3327-3336. ISSN 0039-6028

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Official URL: http://dx.doi.org/10.1016/j.susc.2006.06.034

Abstract

The initial growth of Pt on the Ni(I 10)43 x 1)-O and NiO(110) surfaces has been studied by coaxial impact collision ion scattering spectroscopy (CAICISS), low energy electron diffraction (LEED) and X-ray photoelectron spectroscopy (XPS). Prior to Pt deposition, the atomic structure of the near-surface regions of the Ni(110)-(3 x 1)-O and NiO(110) structures were studied using CAICISS, finding changes to the interlayer spacings due to the adsorption of oxygen. Deposition of Pt on the Ni(110)-(3 x 1)-O surface led to a random substitutional alloy in the near-surface region at Pt coverages both below and in excess of I ML. In contrast, when the surface was treated with 1800 L of atomic oxygen in order to form a NiO(110) surface, a thin Pt layer was formed upon room temperature Pt deposition. XPS and LEED data are presented throughout to support the CAICISS observations. (c) 2006 Elsevier B.V. All rights reserved.

Item Type: Journal Article
Subjects: Q Science > QD Chemistry
Q Science > QC Physics
Journal or Publication Title: Surface Science
Publisher: ELSEVIER SCIENCE BV
ISSN: 0039-6028
Date: 15 August 2006
Volume: 600
Number: 16
Number of Pages: 10
Page Range: pp. 3327-3336
Identification Number: 10.1016/j.susc.2006.06.034
Publication Status: Published
URI: http://wrap.warwick.ac.uk/id/eprint/33077

Data sourced from Thomson Reuters' Web of Knowledge

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