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Carbene or zwitterion? Competition in organoplatinum complexes
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UNSPECIFIED (2006) Carbene or zwitterion? Competition in organoplatinum complexes. DALTON TRANSACTIONS (27). pp. 3321-3325. doi:10.1039/b517874f ISSN 1477-9226.
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Official URL: http://dx.doi.org/10.1039/b517874f
Abstract
The reaction of a known dimeric dicarbene complex of platinum with a number of ligands results in four new platinum complexes. The structure of the new complexes is described: one complex must exist as a neutral complex with no charge separation, and the other three are assigned a charge-separated (zwitterionic) structure, rather than a carbene form, on the basis of comparative C-13 NMR shifts.
| Item Type: | Journal Article | ||||
|---|---|---|---|---|---|
| Subjects: | Q Science > QD Chemistry | ||||
| Journal or Publication Title: | DALTON TRANSACTIONS | ||||
| Publisher: | ROYAL SOC CHEMISTRY | ||||
| ISSN: | 1477-9226 | ||||
| Official Date: | 2006 | ||||
| Dates: |
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| Number: | 27 | ||||
| Number of Pages: | 5 | ||||
| Page Range: | pp. 3321-3325 | ||||
| DOI: | 10.1039/b517874f | ||||
| Publication Status: | Published |
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