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Aggregation of imine-based metallo-supramolecular architectures through pi-pi interactions
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Pascu, Mirela, Clarkson, Guy J., Kariuki, Benson M. and Hannon, M. J. (Michael J.) (2006) Aggregation of imine-based metallo-supramolecular architectures through pi-pi interactions. Dalton Transactions (No.22). pp. 2635-2642. doi:10.1039/b517643c ISSN 1477-9226.
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Official URL: http://dx.doi.org/10.1039/b517643c
Abstract
The design of supramolecular architectures based on isoquinoline-imine ligand systems is described. The isoquinoline affords an extended pi surface and the use of this surface to obtain self-recognition and consequent pi-pi aggregation is investigated. The approach is effective in that each of four complexes is observed to aggregate through these interactions. Other pi-pi interactions can interfere with the aggregation indicating that a larger pi-surface may be required to obtain complete control over the aggregation of the units.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||
Journal or Publication Title: | Dalton Transactions | ||||
Publisher: | Royal Society of Chemistry | ||||
ISSN: | 1477-9226 | ||||
Official Date: | 14 June 2006 | ||||
Dates: |
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Number: | No.22 | ||||
Number of Pages: | 8 | ||||
Page Range: | pp. 2635-2642 | ||||
DOI: | 10.1039/b517643c | ||||
Status: | Peer Reviewed | ||||
Publication Status: | Published | ||||
Access rights to Published version: | Restricted or Subscription Access | ||||
Funder: | Engineering and Physical Sciences Research Council (EPSRC), Siemens Analytical Instruments |
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